Biodiesel
is a mixture of fatty acid alkyl esters (FAAEs) produced
by transesterification, which has been promoted as a substitute for
petroleum diesel in some areas of China. However, it shows poor cold
flow properties (CFPs), such as high pour point, high cloud point,
and high cold filter plugging point, meaning that biodiesel would
crystallize under low-temperature conditions, thus resulting in engine
problems and emission issues. This review focused on the mechanisms
related to the CFPs of biodiesel and outlined the factors that initialize
and accelerate the crystallization process. The influence of CFPs
on engine performance and pollutant emissions was also discussed.
Particular emphasis was given to available methods that can improve
the CFPs of biodiesel. Modifying the composition of FAAEs, changing
the component ratio, and removing minor constituents are three primary
directions. Every derivative method was described in detail about
the characteristics, shortcomings, and what can be improved. The type
and load of cloud point/pour point/cold filter plugging point cold
flow improvers were compared and selected on the basis of the improvement
effect of CFPs. Microemulsion is a new method that may be used to
improve the CFPs of biodiesel. As a result of the variability of the
biodiesel components and the complexity of each improving method on
the overall fuel properties and performance, the CFP modification
methods should be studied and evaluated carefully and comprehensively
before being adopted in industrial applications.