In this study, weather patterns (WPs) associated with the heat wave in South Korea are objectively classified by applying <i>K</i>-means clustering analysis. The representative weather patterns that caused the heat wave were divided into three WPs, namely WP 1, WP 2, and WP 3. The heat wave over the Korean Peninsula was mainly related to the expansion of the North Pacific High (NPH). Moreover, we analyzed the relationship between casualties and WPs of the heat wave. In WP 1, the isobar of NPH was located in the southern part of South Korea. Most casualties (18 people) occurred in this region. In WP 2, NPH was distributed throughout South Korea, with nationwide casualties of 44 people. Moreover, the duration of the heat wave for WP 2 was the longest, at 4.5 days. WP 3 occurred mainly in June, when the NPH was not yet developed, presenting the smallest number of casualties.