Despite
reductions in acidic deposition, high freshwater Al concentrations
continue to threaten acidified ecosystems across the northern hemisphere.
Seasonally elevated Al concentrations may pose a particular threat
to freshwater organisms. Despite this threat, there is a lack of understanding
about the timing and drivers of seasonal Al fluctuations. Here, we
address this knowledge gap by identifying seasonal patterns of Al
and their drivers in 16 rivers across Nova Scotia, Canada. We identify
five distinct Al regimes with different timing of seasonally elevated
Al concentrations. Regimes are distinguished by correlation strength
and direction between Al and base cations, total organic carbon, turbidity,
and discharge. Most notably, regimes are distinguished by a gradient
of Al–base cation decoupling as Ca and Mg concentration approaches
1.4 mg L–1 and 0.6 mg L–1, respectively.
Seasonally elevated Al concentrations exceeded the 0.1–0.2
mg L–1 World Health Organization drinking water
guidelines in all regimes, and inorganic monomeric Al is projected
to exceed the 15 μg L–1 threshold for aquatic
health in most rivers. This research highlights the complexity of
seasonal Al dynamics and the importance of understanding seasonal
variation of Al to quantify the impact of Al on human health, water
treatment, and aquatic organisms.