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Gelled fluids are routinely used in hydraulic fracturing to deliver fractures with higher propped width, due to the fluids' abilities to deliver higher proppant concentrations than their lower-viscosity analogues. The most common of these gels (borate-crosslinked polymers) have been used successfully in fracturing for decades, routinely exhibiting viscosity >100cP in conventional high-pressure, high temperature (HPHT) viscosity measurements. Recent studies have found that the viscosities of borate gels at actual downhole pressure conditions may be 80% less than that measured using standard HPHT rheometer measurement (which uses 400 psi top-pressure). A proposed mechanism for this phenomenon is a pressure-induced shifting of the crosslink/temperature stability near the "melt temperature" of borate-crosslinked gels, leading to a reversible thinning. A novel approach is posed in the current work to exploit the "pressure effect", by capturing the pressure-thinned fluid in a thin state and irreversibly breaking the gel viscosity. As existing crosslinked-gels with oxidative breakers rarely achieve >50% retained pack-permeability, an improved break mechanism based on pressure could yield sizeable productivity-gain in propped fractures. A series of candidate breaker materials with potential affinity for the crosslinker was screened for gel-breaking performance in the current work. Preliminary screening of these additives led to one preferred alternative gel breaker material which demonstrated superior performance in pressure-induced breaking behavior. This study will illustrate advanced characterization of the breaker performance utilizing realistic sequences of temperature, pressure and shear rate that would be expected for a fracturing treatment. The advanced characterization also included fracture-conductivity measurements comparing a control gel with and without the alternative breaker. Under these conditions, the fluids containing the candidate breaker material showed persistent viscosity-break, while the control fluids recovered their viscosities upon pressure-release. The preferred breaker material performance was further confirmed through a series of experimental conditions varying temperature, pressure (up to 10,000 psi), gel concentration, and breaker concentration. In fracture conductivity measurements, the gel which contained the preferred breaker also showed improved conductivity compared to control fluids without breaker. The current study proposes a new method of achieving break of gelled fracturing fluid, which avoids some of the risks and disadvantages of oxidizer chemicals. These results will suggest the most preferred fluid conditions for applying the new breaker material in hydraulic fracturing.
Gelled fluids are routinely used in hydraulic fracturing to deliver fractures with higher propped width, due to the fluids' abilities to deliver higher proppant concentrations than their lower-viscosity analogues. The most common of these gels (borate-crosslinked polymers) have been used successfully in fracturing for decades, routinely exhibiting viscosity >100cP in conventional high-pressure, high temperature (HPHT) viscosity measurements. Recent studies have found that the viscosities of borate gels at actual downhole pressure conditions may be 80% less than that measured using standard HPHT rheometer measurement (which uses 400 psi top-pressure). A proposed mechanism for this phenomenon is a pressure-induced shifting of the crosslink/temperature stability near the "melt temperature" of borate-crosslinked gels, leading to a reversible thinning. A novel approach is posed in the current work to exploit the "pressure effect", by capturing the pressure-thinned fluid in a thin state and irreversibly breaking the gel viscosity. As existing crosslinked-gels with oxidative breakers rarely achieve >50% retained pack-permeability, an improved break mechanism based on pressure could yield sizeable productivity-gain in propped fractures. A series of candidate breaker materials with potential affinity for the crosslinker was screened for gel-breaking performance in the current work. Preliminary screening of these additives led to one preferred alternative gel breaker material which demonstrated superior performance in pressure-induced breaking behavior. This study will illustrate advanced characterization of the breaker performance utilizing realistic sequences of temperature, pressure and shear rate that would be expected for a fracturing treatment. The advanced characterization also included fracture-conductivity measurements comparing a control gel with and without the alternative breaker. Under these conditions, the fluids containing the candidate breaker material showed persistent viscosity-break, while the control fluids recovered their viscosities upon pressure-release. The preferred breaker material performance was further confirmed through a series of experimental conditions varying temperature, pressure (up to 10,000 psi), gel concentration, and breaker concentration. In fracture conductivity measurements, the gel which contained the preferred breaker also showed improved conductivity compared to control fluids without breaker. The current study proposes a new method of achieving break of gelled fracturing fluid, which avoids some of the risks and disadvantages of oxidizer chemicals. These results will suggest the most preferred fluid conditions for applying the new breaker material in hydraulic fracturing.
The fracturing fluid is the essential part of any hydraulic fracturing treatment. A borate-crosslinked guar-based fluid is one of the most commonly used types of fluid. The first mention of guar derivatives crosslinked with boron can be traced back to 1977. Scientific papers that describe boron equilibria as a function of the fluid pH can be trackedback to 1966. Comprehensive studies of the rheological behavior of borate-based fluids were performed in 1980s and 1990s, and for almost 30 years, it has been considered as a well-known topic. Recently, a few authors reported a significant decrease in viscosity of the fluid at elevated pressure. This decrease was reversible (i.e., as soon as the pressure values are moved back to the normal, the viscosity is recovers). Such effect can significantly affect the stimulation design and outcome because most of the time the slurry is affected by elevated temperatures and pressures. Still, many questions remained unanswered. One of them is the effect of crosslinker concentration/composition on the stability of the fluid at highpressure. Another is the comparison of the fluid viscosity under the ISO 13503-1 ramp at standard conditions and elevated pressure. The last one concerns the actual values of the fluid rheological parameters, n and K’, under different pressures. In this paper, we investigate the fracturing fluid behavior under high pressure. For the first time in the industry, we compare the results of ISO fluid stability testing, and the fluid shear recovery under 400-psi pressure and up to 10,500 psi. Finally, using a novel hydraulic fracturing simulator, the effect of the pressure-sensitivity of the fluid on the proppant transport, fracture geometry, and, subsequently, well productivity will be demonstrated. The findings of this paper will have noticeable impact on the design of the hydraulic fracturing treatment where borate-crosslinked fluids are used.
This review is based on latest application of nanoparticles in hydraulic fracturing, and their feasibility as compared to other conventional methods. Focusing on technical, economic, mechanisms and direction of future research. Current status and advancement give a promising future application by using unique properties of nanomaterials such as small sizes, stability, magnetic properties and surface area which are yet to be exploited to full potential. Nano materials can be inculcated in drilling in all forms. From acting as additives in drilling mud there by enhancing density, gel breaking strength, viscosity, acting as a proppant, cross linking agent etc. There are certain problems which are difficult to overcome using macro and micro type additives due to limitations in physical, chemical and environmental characteristics. Hence, the scientists are looking for such smart fluids which can overcome these limitations. Compared to their parent materials, nanoparticles can be modified physically, chemically, electrically, thermally, thermodynamic properties and interaction potential of nanomaterial. However more investment, work and pilot projects are required to understand properties of nanomaterials at reservoir temperature and pressure. Nanomaterials such as aluminium oxide, zinc oxide, copper oxide, silicon dioxide, low cost carbon nanotubes, fly ash nanoparticles in unconventional reservoirs need to be further researched. Moreover, focus should be put on economic analysis, performance at reservoir conditions, cross linking and agglomeration properties, wettability alterations, interfacial tensions properties. The enhanced hydrocarbon recovery from unconventional reservoirs through wettability alterations and interfacial tension decrement by nanomaterials and combined use of fracturing fluid system comprising of VES, foams, proppants gives a promising future application.
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