National Physical Laboratory New Delhi has taken up a program for developing WOLEDs for general lighting applications. In this effort a 1"x1" proto type of a multilayer phosphorescent efficient WOLED has been demonstrated (Fig.2). In this review, we like to highlight on the development of white organic LEDs for general lighting. 2. Basic OLED Structure and Operation principles White organic light emitting diodes are thin-film multilayer devices in which active charge transport and light emitting materials are sandwiched between two thin film electrodes, and at least one of the two electrodes must be transparent to light. Generally high work function (∼4.8 eV), low sheet resistant (20 /□) and optically transparent indium tin oxide (ITO) is used as an anode, while the cathode is a low work function metal such as Ca, Mg, Al or their alloys Mg:Ag, Li:Al. An organic layer with good electron transport and hole blocking properties is typically used between the cathode and the emissive layer. The device structure of an OLED is given in Fig. 3. When an electric field is applied across the electrodes, electrons and holes are injected into states of the lowest unoccupied molecular orbital (LUMO) and the highest occupied molecular orbital (HOMO), respectively and transported through the organic layer. Inside the semiconductor electrons and holes recombine to form excited state of the molecule. Light emission from the organic material occurs when the molecule relaxes from the excited state to the ground state. Highly efficient OLEDs which are being developed at present, contains many layers with different functionality like hole injection layer(HIL), hole transport layer (HTL),electron blocking layer(EBL), emissive layer(EML), hole blocking layer(HBL), electron transport layer(ETL) and electron injection layer(EIL) etc apart from electrodes. A schematic diagram of multilayer structure is shown in Fig. 4.