In this study, the detailed temperature and frequency-dependent (ac) conductivity analyzes of Polypyrrole/Edirne Kufeki Stone (PPy/EKS) composites have been realized by considering both experimental and Machine Learning (ML) algorithms predicted data. In this respect, the experimental ac conductivity data of pure PPy, PPy/5% EKS, PPy/10% EKS, and PPy/20% EKS composites between 1 Hz and 40 MHz at 296, 313, and 333 K temperatures have been usedfor the data set of ML. First, a benchmark study has been done for applied ML algorithms to obtain an eligible model. It is found that the Gaussian process regression (GPR) algorithm provided the best prediction performance. Since it has been observed a good conformity between the experimental and prediction data of GPR model, the ac conductivity (σ ac ) versus angular frequency (w) curves of the composites produced experimentally have been estimated for new temperature values, which were not treated experimentally. Then, the σ ac ¼ f w ð Þ curves of at temperature values have been estimated by GPR which is for the EKS composites at various contributions that have not been experimentally produced. Ultimately, the GPR algorithm developed in the present work enables us to determine the optimum EKS additive percentage, working temperature, and frequency band for the PPy polymer matrix.