Improved Synthesis and Corrosion Properties of Poly(bis-(dialkylamino)phenylene vinylene)s (BAMPPV)

Anderson, Nicole; Irvin, David J.; Irvin, Jennifer A.; Stenger‐Smith, John D.; Guenthner, Andrew J.; Webber, Cindy; Zarras, Peter

doi:10.1021/bk-2003-0843.ch008

Cited by 3 publications

(4 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The BAM-PPV was characterized via 1 H NMR, 13 C NMR and FTIR spectroscopy for structure and elemental analysis for chemical composition. The data was consistent with previous reports on BAM-PPV properties, confirming the product [24,28,29].…”

Section: Polymerization Of 25-bis(chloromethyl)-4-(hexamethylamino)-supporting

confidence: 92%

See 1 more Smart Citation

Laboratory and Field Studies of Poly(2,5-bis(N-methyl-N-hexylamino)phenylene vinylene) (BAM-PPV): A Potential Wash Primer Replacement for Army Military Vehicles

et al. 2014

Self Cite

View full text Add to dashboard Cite

Abstract:In this study, an electroactive polymer (EAP), poly (2,phenylene vinylene) (BAM-PPV), was tested as an alternative to current hexavalent chromium (Cr(VI))-based Army wash primers. BAM-PPV was tested in both laboratory and field studies to determine its adhesive and corrosion-inhibiting properties when applied to steel and aluminum alloys. The Army Research Laboratory (ARL) tests showed that BAM-PPV combined with an epoxy primer and the Army chemical agent-resistant coating (CARC) topcoat met Army performance requirements for military coatings. After successful laboratory testing, the BAM-PPV was then field tested for one year at the Aberdeen Test Center (ATC). This field testing showed that BAM-PPV incorporated into the Army military coating survived with no delamination of the coating and only minor corrosion on the chip sites. OPEN ACCESSCoatings 2014, 4 688

show abstract

Section: Polymerization Of 25-bis(chloromethyl)-4-(hexamethylamino)-supporting

confidence: 92%

“…The monomer, 2,5-bis(chloromethyl)-4-(hexamethylamino)-phenyl)hexamethylamine dihydrochloride, was prepared according to published work [27][28][29]. Acetonitrile, methanol, toluene, tetrahydrofuran (THF) and potassium t-butoxide (K-t-OBu) were obtained from Aldrich Chemical Company and used without further purification.…”

Section: Methodsmentioning

confidence: 99%

Laboratory and Field Studies of Poly(2,5-bis(N-methyl-N-hexylamino)phenylene vinylene) (BAM-PPV): A Potential Wash Primer Replacement for Army Military Vehicles

et al. 2014

Self Cite

View full text Add to dashboard Cite

show abstract

“…The monomer 2,5-bis(chloromethyl)-4-(hexamethylamino)-phenyl)hexamethylamine dihydrochloride and the polymer, BAM-PPV were prepared according to previously reported literature procedures [ 22 , 23 , 24 , 31 , 32 ]. 1-Chloro-4-(trifluomethyl) benzene (Oxsol 100), acetone, methanol, and Alconox were purchased from Aldrich Chemical Company (St. Louis, MO, USA) and used as received.…”

Section: Methodsmentioning

confidence: 99%

Poly(2,5-bis(N-Methyl-N-Hexylamino)Phenylene Vinylene) (BAM-PPV) as Pretreatment Coating for Aerospace Applications: Laboratory and Field Studies

et al. 2014

Self Cite

View full text Add to dashboard Cite

In this study, an electroactive polymer (EAP), poly(2,5-bis(N-methyl-N-hexylamino)phenylene vinylene) (BAM-PPV) was investigated as a potential alternative surface pretreatment for hexavalent chromium (Cr(VI))-based aerospace coatings. BAM-PPV was tested as a pretreatment coating on an aerospace aluminum alloy (AA2024-T3) substrate in combination with a non-Cr(VI) epoxy primer and a polyurethane Advanced Performance Coating (APC) topcoat. This testing was undertaken to determine BAM-PPV’s adhesion, corrosion-inhibition, compatibility and survivability in laboratory testing and during outdoor field-testing. BAM-PPV showed excellent adhesion and acceptable corrosion performance in laboratory testing. The BAM-PPV aerospace coating system (BAM-PPV, non-Cr(VI) epoxy primer and polyurethane APC topcoat) was field tested for one year on the rear hatch door of the United States Air Force C-5 cargo plane. After one year of field testing there was no evidence of delamination or corrosion of the BAM-PPV aerospace coating system.

show abstract

“…Vegetable oils are the most chemically similar compounds to mineral oil and probably have the greatest potential to replace petroleum products (Guner et al, 2006). Recently, conducting polymers (CPs) have attracted much attention from researchers and technologists engaged in the development of novel materials that find application in modern technology due to their nontoxic and eco-friendly nature (DeBerry, 1985;Ahmad and MacDiarmid, 1987;Anderson et al, 2002;Berry et al, 2000). Furthermore, nanostructuring has led to a dramatic improvement in their mechanical, chemical, electronic, magnetic, optic, catalytic and corrosion resistant properties.…”

Section: Introductionmentioning

confidence: 99%

Comparative study of polyaniline and poly(1‐naphthylamine) dispersed oil polyurethane coatings

Riaz

Ashraf²,

Ahmad³

2008

Anti-Corrosion Methods and Materials

View full text Add to dashboard Cite

Purpose -The purpose of this paper is to report a comparative study of conducting polymer (CP) dispersed oil polyurethane coatings derived from a sustainable resource, i.e. polyaniline (PANI)/coconut oil polyesteramide urethane (CPEAU) and poly(1-naphthylamine) (PNA)/linseed oil polyurethane (LPUA) coatings. Design/methodology/approach -The coatings were prepared chemically and were characterized for their physico-chemical, physico-mechanical, corrosion protective efficiency, and open circuit potential measurements. The morphological analysis of the corroded carbon steel (CS), coated uncorroded CS, and coated corroded CS specimens, was carried out by SEM analysis. Findings -The study revealed that the presence of a CP enhanced the corrosion protective efficiency of the sustainable resource-based organic coatings. The type of CP used also played a major role in defining the corrosion resistance behavior of the coating materials. Originality/value -The comparative study of anticorrosive properties of CP with oil-based polyurethane blends has been studied for the first time.

show abstract

Improved Synthesis and Corrosion Properties of Poly(bis-(dialkylamino)phenylene vinylene)s (BAMPPV)

Cited by 3 publications

References 0 publications

Laboratory and Field Studies of Poly(2,5-bis(N-methyl-N-hexylamino)phenylene vinylene) (BAM-PPV): A Potential Wash Primer Replacement for Army Military Vehicles

Laboratory and Field Studies of Poly(2,5-bis(N-methyl-N-hexylamino)phenylene vinylene) (BAM-PPV): A Potential Wash Primer Replacement for Army Military Vehicles

Poly(2,5-bis(N-Methyl-N-Hexylamino)Phenylene Vinylene) (BAM-PPV) as Pretreatment Coating for Aerospace Applications: Laboratory and Field Studies

Comparative study of polyaniline and poly(1‐naphthylamine) dispersed oil polyurethane coatings

Contact Info

Product

Resources

About