A three-dimensional numerical model for thermal-fluid-metallurgical coupling was established to inspect the effect from a stable longitudinal magnetic field on molten pool of magnesium/aluminum laser welding. Magnetic field-assisted laser welding platform was built to test the morphology and spectrum of the metal vapor/plasma. The scanning electron microscope (SEM) and energy dispersive spectrometry (EDS) were used to determine the morphology and element distribution of molten pool cross section. Simulation results showed that temperature gradient of molten pool was reduced, heat distribution became uniform, and keyhole area was enlarged. In addition, the flow velocity of molten pool was increased, the vorticity of molten pool was improved, and the flow region of liquid metal was enlarged. Experimental results showed that penetration of molten pool was deeper, the shape of welding pool tended to be symmetrical and the density of Al element distribution in welding pool was increased by magnetic field. Thus, heat and mass transfer in welding pool was promoted due to the application of magnetic field, the elements exchange and the convection of liquid metal were accelerated, and the distribution of Mg-Al compounds should be dispersed under the agitation of Lorentz force. It's predicted that the distribution of Mg-Al compounds in magnesium/aluminum laser welding would be positively affected by magnetic field, which was beneficial to control the weld quality. Hence, numerical results and experimental verification shared good consistency.