The effects of additive sintering aids on the microstructures and microwave dielectric properties of 0.8(Mg 0.95 Zn 0.05 )TiO 3 -0.2Ca 0.61 Nd 0.26 TiO 3 ceramics were investigated. V 2 O 5 was selected as a liquid phase sintering aid to lower the sintering temperature of 0.8(Mg 0.95 Zn 0.05 ) TiO 3 -0.2Ca 0.61 Nd 0.26 TiO 3 ceramics. With added V 2 O 5 , the densification temperature of 0.8(Mg 0.95 Zn 0.05 )TiO 3 -0.2Ca 0.61 Nd 0.26 TiO 3 can be effectively reduced from 1350 • C to 1175-1275 • C. Low-level doping of V 2 O 5 (0.5-4 wt%) significantly improves the density and dielectric properties of 0.8(Mg 0.95 Zn 0.05 )TiO 3 -0.2Ca 0.61 Nd 0.26 TiO 3 ceramics. The quality factor Q × f was strongly dependent upon the amount of additives. Q × f values of 46,100 and 14,700 GHz could be obtained at 1175-1275 • C with 0.5 and 4 wt% V 2 O 5 added, respectively. Over all ranges of addition, the relative dielectric constants differed significantly and ranged from 20.6 to 26.5. The temperature coefficient varied from −14.9 to 8.91 ppm/ • C.