With the use of variational method to solve the effective mass equation, we
have studied the electronic and shallow impurity states in semiconductor
heterostructures under an applied electric field. The electron energy levels
are calculated exactly and the impurity binding energies are calculated with
the variational approach. It is found that the behaviors of electronic and
shallow impurity states in heterostructures under an applied electric field
are analogous to that of quantum wells. Our results show that with the
increasing strength of electric field, the electron confinement energies
increase, and the impurity binding energy increases also when the impurity
is on the surface, while the impurity binding energy increases at first, to
a peak value, then decreases to a value which is related to the impurity
position when the impurity is away from the surface. In the absence of
electric field, the result tends to the Levine's ground state energy
(-1/4 effective Rydberg) when the impurity is on the surface, and the ground
impurity binding energy tends to that in the bulk when the impurity is far
away from the surface. The dependence of the impurity binding energy on the
impurity position for different electric field
is also discussed.