Boron nitride (BN) interfacial layer with controlled thickness and structure was prepared on the surface of near stoichiometric ratio SiC fiber preforms by a chemical vapor deposition process, and the SiC/SiC composites were obtained by polymer precursor infiltration and pyrolysis process. The microstructure of the BN interfacial layer and SiC/SiC composites was tested by scanning electron microscopy, and the mechanical behavior of SiC/SiC composites was characterized by a mechanical properties test. Results showed that BN interfacial layer was evenly distributed in the fiber preforms with excellent thickness consistency. As the thickness of the BN interfacial layer increased, the deflection path of the crack increased gradually, resulting in the flexural strength first increasing and then decreasing. The mechanical behavior mentioned above was mainly attributed to the dual effects of load transfer and crack propagation of the BN interfacial layer; that was, the crack propagation of ceramic matrix under external load lengthened the path of load transfer and formed a large number of fibers bridging and pulling out successively, which contributed to the energy dissipation mechanism.