In situ assembly of graphene sheets-supported SnS2 nanoplates into 3D macroporous aerogels for high-performance lithium ion batteries

Jiang, Xin; Yang, Xin; Zhu, Yihua; Shen, Jianhua; Fan, Kaicai; Li, Chunzhong

doi:10.1016/j.jpowsour.2013.03.048

Cited by 183 publications

(98 citation statements)

References 58 publications

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“…Regarding the progression of the previously developed hybrids, improved specifi c capacity values were reported through the exploitation of 3D graphene matrixes incorporating, for example, SnO 2 , [252][253][254] Fe 3 O 4 , [ 255,256 ] MoS 2 , [ 257,258 ] SnS 2 , [ 259 ] MnO, [ 260 ] TiO 2 [ 261 ] or Si [ 262 ] particles. Indeed, the graphene network appeared to be benefi cial for reducing the material resistance and to improve the mechanical stability of the electrode.…”

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confidence: 99%

Critical Insight into the Relentless Progression Toward Graphene and Graphene‐Containing Materials for Lithium‐Ion Battery Anodes

et al. 2016

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that its extraordinary properties would enable revolutionary new technologies, which gave birth to the "graphene era". [ 3,4 ] Relying on this scenario, in 2013, the European Union launched the ¤1 billion "Graphene Flagship" project aimed to investigate the properties of this new form of carbon for various applications (e.g., electronics, sensors and energy storage devices), with the ambitious goal of guiding graphene from laboratories to commercial applications within a decade. [ 5,6 ] In the same period, the Chinese Government set up a similar investment to mass-produce graphene as thin fi lms (e.g., for touchscreen electrodes) and platelets (e.g., for use in batteries). [ 6 ] In the following years, hundreds of patents, mainly focused on manufacturing and application in energy storage, were fi led and the worldwide production of graphene and graphene-containing materials rapidly increased. Although a few Chinese industries claimed to already use graphene-containing materials for smartphone production, no revolutionary practical application relying on graphene has been yet developed. [ 6 ] Specifi cally with respect to the battery fi eld, a close analysis of the scientifi c literature reveals a struggle to meet the ambitious initial targets. A potential loss of focus from the fi nal application caused by hype and ease of publication on such a novel matter, together with the delivery of very misleading information [ 7,8 ] and erroneous statements [ 7 ] concerning the use of graphene in batteries are emerging as possible reasons of the ineffective graphene-era outburst. In this progress report, we do not focus on production and classifi cation of graphene and graphene-containing materials, which were already well reported in the past years. [ 3,[9][10][11] In contrast, due to the lack of an exhaustive analysis of the progression of the use of such materials in lithium-ion battery (LIB) anodes, we report here a critical evaluation of the most prominent research papers published from 2008 until the end of 2015. As shown in Figure 1 , three different stages of the graphene research in LIB anodes can be distinguished: a fi rst stationary phase between 2008 and 2010 where the lithium-ion storage properties of different graphene and graphene-containing materials were preliminarily explored, a second exponential stage, spanning from 2010 to 2014, where graphene and graphene-containing anode materials were broadly developed and investigated, and fi nally, a third phase, (i.e., starting from 2015), where the research seems to have approached a plateau. After Used as a bare active material or component in hybrids, graphene has been the subject of numerous studies in recent years. Indeed, from the fi rst report that appeared in late July 2008, almost 1600 papers were published as of the end 2015 that investigated the properties of graphene as an anode material for lithium-ion batteries. Although an impressive amount of data has been collected, a real advance in the fi eld still seems to be missing. In this framework, atten...

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Critical Insight into the Relentless Progression Toward Graphene and Graphene‐Containing Materials for Lithium‐Ion Battery Anodes

et al. 2016

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“…Thus the capacity would become more stable when the side reactions come to a certain to reach an equilibrium. The good electrochemical performances at high current densities of these SnS 2 @C hollow microsphere show their superiority over those previously reported SnS 2 , such as graphene sheets-supported SnS 2 nanoplates in a study by Jiang et al [37]. Therein the discharge capacity of the LIBs decayed from 642 to 240 mA g −1 when the current densities changed from 50 to 1000 mA g −1 .…”

Section: Electrochemical Performancementioning

confidence: 47%

Rational synthesis of SnS2@C hollow microspheres with superior stability for lithium-ion batteries

Yang

Ding

et al. 2017

Sci. China Mater.

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“…Besides MoS 2 , first time 3D mesoporous MoSe 2 /rGO foam was synthesized by hydrothermal method, which was used as anode in LIB [78]. Additionally, L-TMD NSs such as the SnS 2 and WS 2 have also been combined with the 3D porous structure to improve their electrochemical performance [80][81][82][83][84]. Recently, a facile two-step route to synthesize 3D interconnected graphene frameworks embedded with homogeneously distributed SnS 2 nanoplates (SSG) by using GO NSs, SnCl 4 .5H 2 O and L-cys as source materials has reported.…”

Section: D Porous Structures With 2d Graphene/porous Cnfmentioning

confidence: 99%

Advancement in Layered Transition Metal Dichalcogenide Composites for Lithium and Sodium Ion Batteries

Yousaf¹,

Mahmood²,

Wang³

et al. 2016

JEE

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Abstract:With an ever increasing energy demand and environmental issues, many state-of-the-art nanostructured electrode materials have been developed for energy storage devices and they include batteries, supercapacitors and fuel cells. Among these electrode materials, L-TMD (layered transition metal dichalcogenide) nanosheets (especially, S (sulfur) and Se (selenium) based dichalcogenides) have received a lot of attention due to their intriguing layered structure for enhanced electrochemical properties. L-TMD composites have recently been investigated not only as a main charge storage specie but also, as a substrate to hold the active specie. This review highlights the recent advancements in L-TMD composites with 0D (0-dimensional), 1D, 2D, 3D and various forms of carbon structures and their potential applications in LIB (lithium ion battery) and SIB (sodium ion battery).

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In situ assembly of graphene sheets-supported SnS2 nanoplates into 3D macroporous aerogels for high-performance lithium ion batteries

Cited by 183 publications

References 58 publications

Critical Insight into the Relentless Progression Toward Graphene and Graphene‐Containing Materials for Lithium‐Ion Battery Anodes

Critical Insight into the Relentless Progression Toward Graphene and Graphene‐Containing Materials for Lithium‐Ion Battery Anodes

Rational synthesis of SnS2@C hollow microspheres with superior stability for lithium-ion batteries

Advancement in Layered Transition Metal Dichalcogenide Composites for Lithium and Sodium Ion Batteries

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