2016
DOI: 10.1016/j.nanoen.2016.06.023
|View full text |Cite
|
Sign up to set email alerts
|

In-situ FTIR spectroscopic studies of electrocatalytic reactions and processes

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
2

Citation Types

0
83
0

Year Published

2017
2017
2024
2024

Publication Types

Select...
8
1

Relationship

1
8

Authors

Journals

citations
Cited by 139 publications
(83 citation statements)
references
References 137 publications
(124 reference statements)
0
83
0
Order By: Relevance
“…The absorption spectrum is divided into the X-ray Absorption Near-Edge Structure (XANES) region and the Extended X-ray Absorption Fine Structure (EXAFS) region; the former examines the oxidation state, coordination number, electronic configuration and site symmetry, whereas the latter provides information on average interatomic distances. Raman spectroscopy is also used to explore the variation in the local structure and oxidation state, as well as the thermal stability of electrode surfaces or electrode-electrolyte interfaces during charge-discharge and heat treatment (Dokko et al, 2002;Hardwick et al, 2008;Membreno et al, 2013;Stancovski and Badilescu, 2013;Wu et al, 2013); FTIR is another effective tool for studying the surface and evolution of electrodeelectrolyte interfaces under cell operating conditions (Aurbach and Chusid, 1997;Chusid et al, 2001;Cheng et al, 2007;Ye et al, 2016). In addition to these spectroscopic techniques, operando SEM (Miller et al, 2013;Hovington et al, 2014;Marceau et al, 2016) and TEM (Liu, S. et al, 2014;Janish and Carter, 2015;Wang, 2015;Chen et al, 2016a;Xu et al, 2016) show the evolution of direct images of cycling electrode at the micro-and nano-scales.…”
Section: Introductionmentioning
confidence: 99%
“…The absorption spectrum is divided into the X-ray Absorption Near-Edge Structure (XANES) region and the Extended X-ray Absorption Fine Structure (EXAFS) region; the former examines the oxidation state, coordination number, electronic configuration and site symmetry, whereas the latter provides information on average interatomic distances. Raman spectroscopy is also used to explore the variation in the local structure and oxidation state, as well as the thermal stability of electrode surfaces or electrode-electrolyte interfaces during charge-discharge and heat treatment (Dokko et al, 2002;Hardwick et al, 2008;Membreno et al, 2013;Stancovski and Badilescu, 2013;Wu et al, 2013); FTIR is another effective tool for studying the surface and evolution of electrodeelectrolyte interfaces under cell operating conditions (Aurbach and Chusid, 1997;Chusid et al, 2001;Cheng et al, 2007;Ye et al, 2016). In addition to these spectroscopic techniques, operando SEM (Miller et al, 2013;Hovington et al, 2014;Marceau et al, 2016) and TEM (Liu, S. et al, 2014;Janish and Carter, 2015;Wang, 2015;Chen et al, 2016a;Xu et al, 2016) show the evolution of direct images of cycling electrode at the micro-and nano-scales.…”
Section: Introductionmentioning
confidence: 99%
“…There have been few review articles on FTIR's applications in batteries . More articles with technical details of ex situ and in situ FTIR have been published on catalysts …”
Section: Applications Of Ftir Spectroscopy In Secondary Battery Studiesmentioning
confidence: 99%
“…[25] More articles with technical details of ex situ and in situ FTIR have been published on catalysts. [162,164,165]…”
Section: Applications Of Ftir Spectroscopy In Secondary Battery Studiesmentioning
confidence: 99%
“…Operando X-ray diffraction-computed tomography (XRD-CT) [66] and operando hard X-ray microscopy [67] are employed to track space-resolved information, the former probes the crystal structures and transformations at millimeter scale, whereas the latter reveals the dynamic phase transformation process on both single and multi-particles. The diffraction technique measures the collective properties of the electrode, whereas the complimentary information of the local and surface/interface structures, such as the oxidation state of ions, coordination number, average interatomic distances, and electronic configuration changes during the electrochemical process are obtained by operando X-ray absorption spectroscopy (XAS) [68][69][70][71][72][73], Raman spectroscopy [74][75][76][77][78] and Fourier-transform infrared (FTIR) [79][80][81][82]. The electrode changes occurring under working conditions are also observed via operando scanning electron microscopy (SEM) [83][84][85] and (scanning) transmission electron microscopy ((S)TEM) [86][87][88][89][90][91] at the micro-and nano-scales and analyzed with energy dispersive X-ray spectroscopy (EDS), electron energy loss spectroscopy (EELS) and electron diffraction.…”
Section: Introductionmentioning
confidence: 99%