In situ incorporation of nickel nanoparticles into the mesopores of MCM-41 by manipulation of solvent–solute interaction and its activity toward adsorptive desulfurization of gas oil

Textural properties of nickel, palladium and titanium oxides supported on MCM-41 materials and their application on oxidative desulfurization of dibenzothiophene

“…Recent studies have indicated that the transition metals oxides are promising materials for these processes [22][23][24][25][26][27] . However, the use of these materials is limited because the specific surface area, volume and pore diameter are low.…”

“…Moreover, the formation of organic sulfides on the surface for adsorption processes would result in blocking of acid sites in the pores, and hence, decrease in capacity to remove sulfur compounds 22 . Therefore, mesoporous materials of high surface area have been synthesized for use as catalyst support in order to address the shortcomings of d-block transition metals oxides [24][25][26] used for this purpose. The use of supported catalysts containing porous support with an appropriate textural property and containing an active phase based on oxides of the d-block transition metal has been developed.…”

Adsorptive desulfurization using different passivated carbon nanoparticles by PEG-200

“…Activated carbon [11,15,16], zeolite [13,17] and mesoporous materials [6] are the well-known adsorbents. Nano-adsorbents such as nano γ-alumina [18,19] and loaded nanoparticle adsorbents [20] have been recently reported for the removal of organosulfur compounds.…”

H2S Removal Using ZnO/SBA-3: New Synthesis Route and Optimization of Process Parameters

“…The general procedure for synthesis of SBA-3 was reported [45][46][47][48]. In this work, zinc-containing SBA-3 was synthesized via an in situ approach with some modi cations [32]. In a typical synthesis, 3 grams of cetyltrimethylammonium bromide (CTAB) and 150 mL of water were mixed to yield a clear solution.…”

“…It means that H 2 S has remarkable contribution to the amount of emitted SO x into the environment. Subsequently, emitted SO x reacts with water vapor and causes formation of acid rain, which is harmful to mammals and other living organisms [31][32][33]. Removal of H 2 S from a gas stream could be done by several methods, namely, adsorption onto a solid adsorbent, absorption using a liquid solution, and catalytic oxidation [34][35][36][37][38].…”