In situ polymerization of a novel surfactant on a graphene surface for the stable dispersion of graphene in water

Higashi, Chisato; Funasaki, Yuichi; Iguchi, Hiroki; Maruyama, Tatsuo

doi:10.1039/c6ra20315a

Cited by 4 publications

(2 citation statements)

References 34 publications

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“…5a)34. The sheet resistance of the P3HT/graphene composite was 1.8 ± 0.5 kΩsq −1 , which was much smaller than that of the SDS/graphene composite (31.6 ± 3.0 kΩsq −1 ).…”

Section: Resultsmentioning

confidence: 88%

Rational and practical exfoliation of graphite using well-defined poly(3-hexylthiophene) for the preparation of conductive polymer/graphene composite

Iguchi

Higashi

Funasaki

et al. 2017

Sci Rep

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Processing and manipulation of highly conductive pristine graphene in large quantities are still major challenges in the practical application of graphene for electric device. In the present study, we report the liquid-phase exfoliation of graphite in toluene using well-defined poly(3-hexylthiophene) (P3HT) to produce a P3HT/graphene composite. We synthesize and use regioregular P3HT with controlled molecular weights as conductive dispersants for graphene. Simple ultrasonication of graphite flakes with the P3HT successfully produces single-layer and few-layer graphene sheets dispersed in toluene. The produced P3HT/graphene composite can be used as conductive graphene ink, indicating that the P3HT/graphene composite has high electrical conductivity owing to the high conductivity of P3HT and graphene. The P3HT/graphene composite also works as an oxidation-resistant and conductive film for a copper substrate, which is due to the high gas-barrier property of graphene.

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“…5a)34. The sheet resistance of the P3HT/graphene composite was 1.8 ± 0.5 kΩsq −1 , which was much smaller than that of the SDS/graphene composite (31.6 ± 3.0 kΩsq −1 ).…”

Section: Resultsmentioning

confidence: 88%

Rational and practical exfoliation of graphite using well-defined poly(3-hexylthiophene) for the preparation of conductive polymer/graphene composite

Iguchi

Higashi

Funasaki

et al. 2017

Sci Rep

Self Cite

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show abstract

“…Graphite usually exhibits a sharp diffraction peak at 26° 2θ, which is the (002) diffraction of graphite and arises from the interlayer distance between ) Dispersant graphene sheets [57,58]. The graphite flakes exhibited a weak broad diffraction at 20-30° 2θ [59].…”

Section: X-ray and Thermogravimetric Analyses Of The P3ht/graphene Co...mentioning

confidence: 99%

Preparation of uncurled and planar multilayered graphene using polythiophene derivatives via liquid-phase exfoliation of graphite

et al. 2018

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Evaluation of CNT/GNP’s synergic effects on the Mechanical, Microstructural, and durability properties of a cementitious composite by the novel dispersion method

Abedi

Fangueiro

Camões

et al. 2020

Construction and Building Materials

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In situ polymerization of a novel surfactant on a graphene surface for the stable dispersion of graphene in water

Abstract: A graphene surface is functionalized with a polymerizable surfactant by in situ polymerization for the stable colloidal dispersion of graphene.

Cited by 4 publications

References 34 publications

Rational and practical exfoliation of graphite using well-defined poly(3-hexylthiophene) for the preparation of conductive polymer/graphene composite

Rational and practical exfoliation of graphite using well-defined poly(3-hexylthiophene) for the preparation of conductive polymer/graphene composite

Preparation of uncurled and planar multilayered graphene using polythiophene derivatives via liquid-phase exfoliation of graphite

Evaluation of CNT/GNP’s synergic effects on the Mechanical, Microstructural, and durability properties of a cementitious composite by the novel dispersion method

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