“…The diffuse reflectance spectrum of as-prepared Cu 2 O has a broad absorption in the visible range with a characteristic peak at 485 nm, and two subpeaks at 335 and 421 nm that may be attributed to free excitons [27]. Clearly, the absorption onset of pure Cu 2 O was at approximately 650 nm, which agreed well with a bandgap of 1.9 eV, which is in accord with the reported value [28]. It has also been reported that for Cu 2 O NPs with size of about 2-3 nm, the band gap might increase to 2.40 eV due to quantum size effect [29,30].…”