Boron carbide and Tantalum boride composites were prepared by pressureless sintering of B 4 C with addition of TaC powder. The effect of TaC addition on the sinterability of boron carbide was studied. High densified ceramic with a relative density of 98.7% was obtained at sintering temperature of 2250°C. The composition and the microstructure of the dense composites are characterized by means of x-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive x-ray spectroscopy (EDX). The studies show that the composites contain boron carbide, TaB 2 , and carbon phases with a homogeneous structure. In addition, the correlation between the composition and the electrical conductivity was investigated. The electrical conductivity of the composite increased with increasing addition of TaC, and a change in conduction behavior from semiconducting to metallic was observed.High hardness value of 28.49 ± 1.33 GPa was obtained by the sample with 30 wt% TaC addition. K E Y W O R D S boron carbide, electrical conductivity, pressureless sintering, tantalum boride How to cite this article: Martin H-P, Feng B, Michaelis A. Pressureless sintering and properties of boron carbide composite materials. Int J Appl Ceram Technol.