In situ synthesis of a Cu-BTC metal–organic framework (MOF 199) onto cellulosic fibrous substrates: cotton

In situ green preparation and antibacterial activity of copper-based metal–organic frameworks/cellulose fibers (HKUST-1/CF) composite

“…Therefore, a novel MOF/CF composite has been studied and developed in recent years (Küsgens et al 2009;da Silva Pinto et al 2012;Rodriguez et al 2014;Lange and Obendorf 2015;Chui et al 1999).…”

“…Kusgens et al (2009) achieved the synthesis of HKUST-1 on pulp fibers with EtOH/DMF (dimethylformamide) as solvent at 358 K in a 400 ml Teflon-lined steel vessel for 24 h. da Silva Pinto et al (2012) made cotton carboxymethylated with chloroacetate salt to promote the anchor of copper ions first, and then utilized DMF, methanol and water as solvent to syntheze HKUST-1 on cellulose substrate. Based on the recognized ability of HKUST-1 to capture gases and toxic chemicals, combined with Cellulose the availability of cellulose-based fibrous materials, the described procedure provided the basis for future fabrication of functionalized fibers and active filtration media.…”

A new carboxyl-copper-organic framework and its excellent selective absorbability for proteins

“…A different N1s:C1s ratio of 0.16 was observed for BSA-stained compound 1, 0.23 for lysozyme-stained compound 1, indicating that protein adsorption changed the surface chemical compositions and more nitrogen was introduced. The low-resolution XPS survey spectrum of BSAstained compound 1 has a peak of Cu 2p [25], which could be also showed in the pictures (Fig. S2, in supporting information).…”

Ein Chitin‐MOF‐Kompositmaterial mit hierarchischem Porensystem für Anwendungen in der Luftfiltration

“…[20] Aufeinem Gewebe aus Cellulose konnte eine Cu 3 BTC 2 -Beladung von 1.7 Gew.-%( berechnet aus dem Kupfergehalt von 0.5 %) erzielt werden. [21] Abbasi et al konnten Cu 3 BTC 2 ,López-Maya et al UiO-66 auf Seidenfasern aufbringen. Beide Gruppen erhielten Beladungen von ca.…”