2016
DOI: 10.1002/chem.201602599
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Incorporation of N‐Methyl‐d‐glucamine Functionalized Oligomer into MIL‐101(Cr) for Highly Efficient Removal of Boric Acid from Water

Abstract: Polymeric resins are practically important adsorbents in a wide variety of applications, but they generally suffer from low surface areas and limited functionalized adsorption sites owing to their closely compacted and tangled polymeric chains. A metal-organic framework (MOF)-polymer composite with enhanced adsorption capacity against the compacted polymeric resins was reported. The strategy to incorporate functionalized oligomer within the cavities of the MOF was demonstrated by the preparation of MIL-101(Cr)… Show more

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Cited by 18 publications
(5 citation statements)
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“….4°, suggesting a partially crystalline structure and a highly doped emeraldine salt form [46]. All the XRD peaks for MIL-101 match well with the previously reported results by G. Férey et al, evidencing that MIL-101 was successfully synthesized [35,36,42,47,48]. However, it can be seen that the peak between 4 and 8°of MIL-101 almost disappeared after loading PANI.…”
Section: Preparation Of Flexible Solid-state Supercapacitorssupporting
confidence: 89%
See 1 more Smart Citation
“….4°, suggesting a partially crystalline structure and a highly doped emeraldine salt form [46]. All the XRD peaks for MIL-101 match well with the previously reported results by G. Férey et al, evidencing that MIL-101 was successfully synthesized [35,36,42,47,48]. However, it can be seen that the peak between 4 and 8°of MIL-101 almost disappeared after loading PANI.…”
Section: Preparation Of Flexible Solid-state Supercapacitorssupporting
confidence: 89%
“…Afterwards, two electrodes and one polypropylene film filled with gel electrolyte were stacked together face-to-face to assemble the flexible solid-state supercapacitors (SCs). [41,42]. For the PANI/MIL-101 nanocomposites, characteristic peaks of PANI and MIL-101 can be found in the FT-IR spectra, verifying the successful polymerization of aniline in the presence of MIL-101.…”
Section: Preparation Of Flexible Solid-state Supercapacitorsmentioning
confidence: 64%
“…Hence, designing a MOF-polymer composite with enhanced adsorption capacity is in high demand. Wang et al [95] reported the boron adsorption properties of an NMDGfunctionalized oligomer supported on the nanocavities of the highly porous chromium-based MOF, MIL-101. The maximum functionalization of the MOF pores using NMDG was 2.23 mmol/g, which gave a high boron adsorption capacity of 24.7 mg-B/g.…”
Section: Porous Adsorbentsmentioning
confidence: 99%
“…Adapted with permission from Ref. [ 93 ]. Copyright 2016, copyright Wiley-VCH Verlag GmbH & Co. KGaA.…”
Section: Figurementioning
confidence: 99%