1980
DOI: 10.1007/bf00937334
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Indirect electrolytic oxidation of some aromatic derivatives

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Cited by 62 publications
(31 citation statements)
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“…The first proposed industrial applications for Ce(IV) electrogeneration in MEO synthesis involved the production of 1,4-dichlorobutane and 1,6-dichlorohexane for nylon manufacture in the presence of methanesulfonate ions [23] and later the synthesis of aromatic aldehydes in a perchloric acid electrolyte (which can be particularly dangerous in large-scale industrial operations) [101]. Due to the requirement of safer conditions and higher concentration of organic compounds, nitric acid was proposed as solvent for anodic Ce(IV) generation, at the cost of noxious NOx formation [24].…”
Section: Mediated Electrosynthesismentioning
confidence: 99%
“…The first proposed industrial applications for Ce(IV) electrogeneration in MEO synthesis involved the production of 1,4-dichlorobutane and 1,6-dichlorohexane for nylon manufacture in the presence of methanesulfonate ions [23] and later the synthesis of aromatic aldehydes in a perchloric acid electrolyte (which can be particularly dangerous in large-scale industrial operations) [101]. Due to the requirement of safer conditions and higher concentration of organic compounds, nitric acid was proposed as solvent for anodic Ce(IV) generation, at the cost of noxious NOx formation [24].…”
Section: Mediated Electrosynthesismentioning
confidence: 99%
“…More recent studies have been published by Wendt et al [2][3][4] and by Kramer et al [5], and a summary of the principal characteristics of aryl aldehyde electrosynthesis can be found in [6]. Industrial interest in the synthesis is mainly due to the widespread use of functionalised aldehydes in fine chemistry.…”
Section: Introduction and Objectivesmentioning
confidence: 99%
“…The application of electrochemical oxidation methods for the treatment of pollutants has been attracted much more interest since it uses a clean reagent 'the electron'. The methods can be employed in oxidation of many different types of organic substrates [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15], recirculation of spent Cr-etching solutions containing high concentrations of Cr(III) [16,17], removal of hydrogen sulfide from the atmosphere [18], removal of SO 2 and NOx from waste gases [19]. The electrochemical treatment of organic and inorganic substrates could be carried out by direct electrochemical oxidation (DEO) or mediated electrochemical oxidation (MEO), such as the degradation of phenol [1,[3][4][5], ␤-dicarbonyl [6], aromatic derivatives [7], EDTA [10,11], pesticides [15] and removal of H 2 S/NO 2 [18,19].…”
Section: Introductionmentioning
confidence: 99%