Induced-current-generated System Using the Chemomechanical Transduction at a Nitrobenzene/Water Interface

Matsushita, Sachiko; Yoshida, Kaori; Sato, Tetsuya; Suga, Yoshihiro

doi:10.1246/cl.2009.110

Cited by 3 publications

(1 citation statement)

References 13 publications

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“…Reported applications of such spontaneous interfacial motion include the extraction of dynamics energy [5,8], generation of biological models [9], and development of a new model of nonequilibrium physics described in the context of electric capillary force [10]. For applying this phenomenon in engineering, information regarding the kind of material that can be used is very important.…”

Section: Introductionmentioning

confidence: 99%

Spontaneous interfacial tension changes at the interface of a ZnCl2 nitrobenzene solution and aqueous stearyltrimethylammonium chloride solution

Tsuruki¹,

Yoneda²,

Shibuya³

et al. 2013

Colloids and Surfaces A: Physicochemical and Engineering Aspect

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Section: Introductionmentioning

confidence: 99%

Spontaneous interfacial tension changes at the interface of a ZnCl2 nitrobenzene solution and aqueous stearyltrimethylammonium chloride solution

Tsuruki¹,

Yoneda²,

Shibuya³

et al. 2013

Colloids and Surfaces A: Physicochemical and Engineering Aspect

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Activation of the spontaneous motion of a nitrobenzene droplet by chlorobenzene blending

Matsushita

Tanaka

Yoshida

et al. 2012

Colloids and Surfaces A: Physicochemical and Engineering Aspect

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Spontaneous Interfacial Tension Changes at the Interface of Metal Chloride Nitrobenzene Solution and Aqueous Stearyltrimethylammonium Chloride Solution: the Role of Metal Ions

Arai

Tsuruki

Isobe

et al. 2017

Bulletin of the Chemical Society of Japan

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The authors examine the roles of chemical compounds that can generate spontaneous interface motion, especially in the Nakache and Dupeyrat system, which normally uses a stearyltrimethylammonium chloride (STA-Cl) aqueous solution and a KI + I2 nitrobenzene solution. The authors observed spontaneous behavior at the interface of a system comprising the STA-Cl aqueous solution and a nitrobenzene solution of ZnCl2 or FeCl3. To investigate the role of metal ions, in-situ electrochemical measurements of systems of various metal halides, such as KCl, CaCl2, AlCl3, ZnCl2, and FeCl3, were conducted and discussed regarding the relationship of the spontaneous interface motion with the consideration of standard Gibbs energy of surfactant adsorption, solubility into the oil phase, and hydration enthalpy. The importance of electric potential dependence of surfactant adsorption–desorption at the oil/water interface is suggested and supported using an FeCl3 chlorobenzene solution. A material design with the consideration of a potential barrier of surfactant desorption would enable us to obtain a spontaneous motion system not utilizing toxic substances.

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Induced-current-generated System Using the Chemomechanical Transduction at a Nitrobenzene/Water Interface

Cited by 3 publications

References 13 publications

Spontaneous interfacial tension changes at the interface of a ZnCl2 nitrobenzene solution and aqueous stearyltrimethylammonium chloride solution

Spontaneous interfacial tension changes at the interface of a ZnCl2 nitrobenzene solution and aqueous stearyltrimethylammonium chloride solution

Activation of the spontaneous motion of a nitrobenzene droplet by chlorobenzene blending

Spontaneous Interfacial Tension Changes at the Interface of Metal Chloride Nitrobenzene Solution and Aqueous Stearyltrimethylammonium Chloride Solution: the Role of Metal Ions

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