Inelastic scattering and satellite fine structure in the high-resolution uv photoelectron spectrum of CS2

Reineck, I.; Wannberg, B.; Veenhuizen, Hans; Nohre, C.; Maripuu, Rein; Norell, Karl Erik; Mattsson, Lars; Karlsson, Leif; Siegbahn, Kai

doi:10.1016/0368-2048(84)80068-7

Cited by 21 publications

(24 citation statements)

References 17 publications

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“…In this paper, we use the molecules GO 2 , COS, and CS 2 to demonstrate the capabilities of the technique. The above-mentioned advantages are fully realized: the spin-orbit split components in all the II bands are completely resolved, and the inelastic scattering features in the R and bands of CO and CS [19,28,29] are completely removed.…”

Section: Introductionmentioning

confidence: 86%

“…Some vibrational assignments have also been controversial [34,39]. Pressure dependent studies have been conducted for CO and C4, and the inelastic scattering features in the R and bands have been confirmed [19,29].…”

Section: Introductionmentioning

confidence: 99%

“…The photoelectron spectra of CO 3 COS, and CS have been extensively studied since the beginning of the fie]d [30][31][32][33][34] and are still under study [19,28,29,[35][36][37][38][39][40][41][42][43]. The isoelectronic structures of the three molecules are ideal for observing any systematic changes.…”

Section: Introductionmentioning

confidence: 99%

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High resolution UV photoelectron spectroscopy of CO+2, COS+ and CS+2 using supersonic molecular beams

Wang

Reutt

Lee

et al. 1988

Journal of Electron Spectroscopy and Related Phenomena

158

111

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Section: Introductionmentioning

confidence: 86%

Section: Introductionmentioning

confidence: 99%

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High resolution UV photoelectron spectroscopy of CO+2, COS+ and CS+2 using supersonic molecular beams

Wang

Reutt

Lee

et al. 1988

Journal of Electron Spectroscopy and Related Phenomena

158

111

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“…This ionic state is split into two spin-orbit components, of which the 2 ⌸ g3/2 state is lower in energy. High resolution photoelectron spectroscopy ͑PES͒ [31][32][33] and, particularly, recent zero kinetic energy ͑ZEKE͒ photoelectron studies 34 have established a value of 81 286Ϯ5 cm Ϫ1 for this lowest ionization limit, a spin-orbit splitting of 440 cm…”

Section: Introductionmentioning

confidence: 99%

Resonance enhanced multiphoton ionization spectroscopy of carbon disulphide

Morgan

Baldwin

Orr‐Ewing

et al. 1996

The Journal of Chemical Physics

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Rydberg excited states of the CS 2 molecule in the energy range 56 000-81 000 cm Ϫ1 have been further investigated via the two and three photon resonance enhancements they provide in the mass resolved multiphoton ionization ͑MPI͒ spectrum of a jet-cooled sample of the parent molecule. Spectral interpretation has been aided by parallel measurements of the kinetic energies of the photoelectrons that accompany the various MPI resonances. Thus we have been able to extend, and clarify, previous analyses of the tangled spin-orbit split vibronic structure associated with the

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“…In the photoelectron spectrum of the CS 2 molecule as recorded by Turner (1970) and Asbrink and coworkers (Schirmer et al 1979) or Reineck et al (1984) one observes below 20 eV four ionic main states and, in addition, two satellite lines at 14·1 and 17·1 eV. At higher energy (i.e.…”

Section: Low Energy Satellite Lines Of Csmentioning

confidence: 90%

Recent Progress in a Green's Function Method for the Calculation of Ionisation Spectra

Niessen¹,

Tomasello²,

Schirmer³

et al. 1986

Aust. J. Phys.

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The ADC( n) approximation scheme to the one-particle Green function is briefly outlined [ADC( n) stands for algebraic diagrammatic construction accurate to nth order of perturbation theory]. The solution of the equations can be done either by a pole search algorithm (PSA) or by the Davidson diagonalisation approach CDDA) whose problems and advantages are discussed. The results obtained for N 2 are compared. The methods are applied to interpret the ionisation spectra of p-quinodimethane, p-benzoquinone and to calculate the lowest ionisation energies of the transition metal diatomics CU2, Ag 2 , Cr2 and M0 2 . The ADC(4) equations are computationally very demanding and additional approximations need to be introduced in order to apply this method to any but the smallest systems. Such a simplified model is presented and applied to N2 and CS 2 .

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Inelastic scattering and satellite fine structure in the high-resolution uv photoelectron spectrum of CS2

Cited by 21 publications

References 17 publications

High resolution UV photoelectron spectroscopy of CO+2, COS+ and CS+2 using supersonic molecular beams

High resolution UV photoelectron spectroscopy of CO+2, COS+ and CS+2 using supersonic molecular beams

Resonance enhanced multiphoton ionization spectroscopy of carbon disulphide

Recent Progress in a Green's Function Method for the Calculation of Ionisation Spectra

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