The polarization of the 21-cm radiation from the epoch of reionization arises from Thomson scattering of 21-cm photons from free electrons and provides information that complements that from the intensity fluctuation. Previous work showed that a direct detection of this signal will be difficult, and hinted that the signal might be enhanced via correlation with other tracers. Here, we discuss the cross-correlation between the cosmic microwave background (CMB) polarization and the 21-cm polarization. We treat reionization using an analytical model with parameters calibrated by seminumerical simulations. We then derive the cross-correlation angular power spectrum using the totalangular-momentum formalism. We also provide a noise analysis to test against two closely related, but subtly different, null hypotheses. First, we assume no reionization as a null hypothesis, and determine how well this null hypothesis could be ruled out by an observed 21cm-CMB polarization correlation. Second, we determine how well the null hypothesis of no 21-cm polarization can be ruled out by seeking the cross-correlation, assuming reionization is established from the CMB. We find that the first question could be answered by a synergy of ambitious next-generation 21-cm and CMB missions, whereas the second question will still remain out of reach.