Natural-superlattice-structured/Intergrowth CaBi 2 Nb 2 O 9-Bi 4 Ti 3 O 12 (CBNO-BIT) ferroelectric thin films were successfully prepared via a magnetron sputtering process. XRD and TEM analysis revealed the [Bi 2 O 2-(CaNb 2 O 7)-Bi 2 O 2-(Bi 2 Ti 3 O 10)] n intergrowth structure of the film, as well as a