Influence of hydrogen bonding on some physical constants of oxamides and thiooxamides

Beukeleer, Sabrina H. J. De; Janssens, J.; Desseyn, H. O.

doi:10.1007/bf01979266

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Cited by 10 publications

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“…A remarkable characteristic of these ligands is their thermal and chemical stability and especially their dissociation constants ,− …”

Section: Introductionmentioning

confidence: 99%

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Theoretical, Structural, Vibrational, NMR, and Thermal Evidence of the Inter- versus Intramolecular Hydrogen Bonding in Oxamides and Thiooxamides

et al. 2004

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This contribution describes the study of hydrogen bonding in secondary oxamides, monothiooxamides, and dithiooxamides by ab initio calculations, X-ray diffractions, NMR spectra, thermal analysis, and variabletemperature infrared and Raman spectroscopy. The results can all be interpreted as a function of the change in the strength and the nature of the hydrogen bonding by substituting oxygen for sulfur in the series CH 3 -HNCOCONHCH 3 , CH 3 HNCSCONHCH 3 , CH 3 HNCSCSNHCH 3 and by changing the steric influence of the alkyl group in a series of oxamides (RHNCOCNHR; R ) CH 3 , C 2 H 5 , iC 3 H 7 , tC 4 H 9 ).

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“…A remarkable characteristic of these ligands is their thermal and chemical stability and especially their dissociation constants ,− …”

Section: Introductionmentioning

confidence: 99%

“…25 The very important role of hydrogen bonding in these various characteristics has been extensively studied. 5,[26][27][28][29][30][31][32]…”

Section: Introductionmentioning

confidence: 99%

Theoretical, Structural, Vibrational, NMR, and Thermal Evidence of the Inter- versus Intramolecular Hydrogen Bonding in Oxamides and Thiooxamides

et al. 2004

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Influence of hydrogen bonding on the thermal behaviour of some amides and thioamides

et al. 2003

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Vibrational and structural evidence of phase transitions in some amides

Desseyn¹,

Clou²,

Janssens³

et al. 2003

Thermochimica Acta

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Influence of hydrogen bonding on some physical constants of oxamides and thiooxamides

Abstract: The influence of intermolecular hydrogen bonding on some physical constants is clearly shown by comparing some thermal data for simple oxamides and thiooxamides.

Cited by 10 publications

References 19 publications

Theoretical, Structural, Vibrational, NMR, and Thermal Evidence of the Inter- versus Intramolecular Hydrogen Bonding in Oxamides and Thiooxamides

Theoretical, Structural, Vibrational, NMR, and Thermal Evidence of the Inter- versus Intramolecular Hydrogen Bonding in Oxamides and Thiooxamides

Influence of hydrogen bonding on the thermal behaviour of some amides and thioamides

Vibrational and structural evidence of phase transitions in some amides

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