Influence of Inclusions in the Corrosion Behavior of Plasma Nitrided Stainless Steel

Abstract

Plasma nitriding is a well‐established technique to improve hardness and tribological properties of austenitic stainless steel. It is proved that it is also possible to preserve the corrosion resistance after nitriding by controlling the process parameters such as time and temperature, obtaining the so‐called S phase. Herein, the corrosion behavior is evaluated for nitrided layers produced by three different plasma treatments: DC plasma nitriding, plasma immersion ion implantation (PIII), and low‐energy ion implantation (LEII), using different parameters in order to obtain the S‐phase in thickness from 1.2 to about 6 μm without nitride precipitation. The microstructure and chemical composition of the nitrided layers is characterized by means of X‐ray diffraction, secondary‐ion mass spectroscopy, and scanning electron microscopy–focused ion beam. The corrosion behavior is evaluated by means of the cyclic polarization tests in NaCl solution. The morphology of the corrosion attack is studied by optical microscopy and SEM‐FIB, revealing a change from crevice to pitting after the nitriding process. The inclusions are observed to be corrosion initiation sites. Due to this, the thickest nitrided layers (with high N concentration) show better corrosion behavior than the thinner ones.

The Corrosion Behavior in Different Environments of Austenitic Stainless Steels Subjected to Thermochemical Surface Treatments at Low Temperatures: An Overview

“…The effect of inclusions, such as MnS, on the corrosion resistance of the modified surface layers, consisting of N-rich expanded austenite, was recently studied [160]. The inclusions appeared to be pitting initiation sites, but they did not cause pitting or crevice in the expanded austenite.…”

Influence of Quenching and Tempering on the Tribological and Corrosion Behavior of Plasma‐Nitrided Society of Automotive Engineers 52100

“…[4] In addition, corrosive environments can aggravate the deterioration of these elements. [5,6] The failure of these elements causes significant losses in the production process due to the stoppage of the machine store, placing the damaged bearing and adjacent elements. [7,8] Therefore, it is necessary to use surface technology to improve the mechanical properties and tribological behavior of SAE 52100 steel.…”