An essential problem of current construction engineering is the search for ways to obtain lightweight building structures with improved characteristics. The relevant way is the use of polymer composite reinforcement and concrete with high classes and prime characteristics. The purpose of this work is the theoretical and experimental substantiation of the effectiveness of combined-reinforced glass fiber polymer composite concrete (GFPCC) bending elements, and new recipe, technological and design solutions. We theoretically and experimentally substantiated the effectiveness of GFPCC bending elements from the point of view of three aspects: prescription, technological and constructive. An improvement in the structure and characteristics of glass fiber-reinforced concrete and GFPCC bending elements of a new type has been proven: the compressive strength of glass fiber-reinforced concrete has been increased up to 20%, and the efficiency of GFPCC bending elements is comparable to the concrete bending elements with steel reinforcement of class A1000 and higher. An improvement in the performance of the design due to the synergistic effect of fiber reinforcement of bending elements in combination with polymer composite reinforcement with rods was revealed. The synergistic effect with optimal recipe and technological parameters is due to the combined effect of dispersed fiber, which strengthens concrete at the micro level, and polymer composite reinforcement, which significantly increases the bearing capacity of the element at the macro level. Analytical dependences of the type of functions of the characteristics of bent concrete structures on the arguments—the parameters of the combined reinforcement with fiber and polymer composite reinforcement—are proposed. The synergistic effect of such a development is described, a new controlled significant coefficient of synergistic efficiency of combined reinforcement is proposed. From an economic point of view, the cost of the developed elements has been reduced and is economically more profitable (up to 300%).