2001
DOI: 10.1080/07370650108216132
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Influence of metal salts of 4-(2, 4, 6-trinitroanilino) benzoic acid on the burnining rate of double base propellants

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Cited by 16 publications
(9 citation statements)
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“…In order to study the effects of bta salts on the thermal decomposition of AP, we choose metal lead(II) on the basis of the following considerations: (1) Lead(II) shows good catalytic performances for propellants. [23] (2) Lead(II), as a result of the stereochemical activity of the lone electron pair, possesses a large radius, a variable stereochemical activity, and a flexible coordination mode. [24][25][26] 2 ]·2H 2 O (3) (bpy = 2,2Ј-bipyridine, phen = 1,10-phenanthroline).…”
Section: Introductionmentioning
confidence: 99%
“…In order to study the effects of bta salts on the thermal decomposition of AP, we choose metal lead(II) on the basis of the following considerations: (1) Lead(II) shows good catalytic performances for propellants. [23] (2) Lead(II), as a result of the stereochemical activity of the lone electron pair, possesses a large radius, a variable stereochemical activity, and a flexible coordination mode. [24][25][26] 2 ]·2H 2 O (3) (bpy = 2,2Ј-bipyridine, phen = 1,10-phenanthroline).…”
Section: Introductionmentioning
confidence: 99%
“…[13][14][15][16][17][18][19] We anticipate salts of BDT would work as 3-nitro-1,2,4-triazol-5-one (NTO) compounds, 20,21 which affect the thermolysis of AP. In order to study the effects of BDT salts on the thermal decomposition of AP, we choose metal lead(II) and manganese(II) on the basis of the following considerations: (1) Lead(II) shows good catalytic performances for propellants; 22 (2) lead(II), as a result of the stereochemical activity of the lone electron pair, possesses a large radius, a variable stereochemical activity, and a flexible coordination mode; [23][24][25] (3) lead(II) and manganese(II) compounds with BDT remain unexplored although extensive studies on salts of BDT have been reported; (4) on the basis of environmental concerns, the Mn(II) is regarded as a less toxic metal ion when compared with Ba(II), Pb(II), and Hg(II) in search of new clean metal-containing energetic materials.…”
Section: Introductionmentioning
confidence: 99%
“…The acidic nature of NTO favours the formation of a large number of salts [6]. Transition metal salts of 2,4,6-trinitroanilinobenzoic acid (TABA) were found promising for double base system in the studies conducted by Pundlik et al [7].…”
Section: Introductionmentioning
confidence: 98%