“…Nitrogen dioxide and volatile organic compounds (i.e., primary pollutants) in presence of stagnant high‐pressure, strong solar radiation, and high air temperature—typical features of UHI—trigger complex chemical reactions which give rise to O 3 formation (Stone, ) (i.e., a secondary pollutant) and limit its dissipation (Li, Song, Mao, Liu, & Huang, ; Ooka et al., ). Although O 3 formation follows complex and nonlinear dynamics—to which contribute numerous factors like the concentration of its precursors, humidity, and solar intensity (Comrie, )—high temperature is a key driver because it accelerates its generation (Tao, Larson, Wuebbles, Williams, & Caughey, , ).…”