The microstructure, mechanical properties and thermal stability of Al x Ti 1− x N and Al 1 Ti 1-x BN coatings grown by reactive high-power impulse magnetron sputtering (HiPIMS) have been analyzed as a function of Al/(Al + Ti) ratio (x) between 0.5 and 0.8. The coatings were predominantly formed by a face-centered cubic Ti(Al)N crystalline phase, both with and without B, even for x ratios as high as 0.6, which is higher than the ratio typically encountered for Al x Ti 1− x N coatings deposited by reactive magnetron sputtering. B doping, in combination with the highly energetic deposition conditions offered by HiPIMS, results in the suppression of the columnar grain morphology typically encountered in Al x Ti 1− x N coatings. On the contrary, the Al x Ti 1− x BN coatings grown by HiPIMS present a dense nanocomposite type microstructure, formed by nanocrystalline Ti(Al) N domains and amorphous regions composed of Ti(Al)B 2 and BN. As a result, high-Al content (x ≈ 0.6) Al x-Ti 1− x BN coatings grown by HiPIMS offer higher hardness, elasticity and fracture toughness than Al x Ti 1− x N coatings. Moreover, the thermal stability and the hot hardness are substantially enhanced, delaying the onset of formation of the detrimental hexagonal AlN phase from 850 • C in the case of Al 0.6 Ti 0.4 N, to 1000 • C in the case of Al 0.6 Ti 0.4 BN.