“…Engineering two-dimensional materials’ electronic structure has been one of the key issues since their isolation, starting with graphene and followed by metal dichalcogenides layers and elemental two-dimensional materials [ 1 , 2 , 3 ], leveraging the benefits of the materials’ two-dimensional nature. Extensive experimental and theoretical studies are being carried out to approach the management of the materials’ band gap, govern the position of the Fermi level, and arrange the density of states (DOS) in the valence and conduction bands [ 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 ]. Several strategies have been advanced for these purposes—structural nanopatterning [ 5 , 6 ], the formation of Moiré heterostructures [ 7 , 8 ], doping with pnictogen or chalcogen atoms [ 9 ], and chemical functionalization [ 1 , 10 , 11 ].…”