Aluminum (Al) alloy surfaces are prone to serious corrosion
in
humid and salt-laden environments, which promotes the development
of numerous protective approaches. Although the amorphous state is
more conducive to improve corrosion resistance compared with the crystalline
state, it still faces coating design problems like insufficient adhesive
strength and flaking-off tendency. Here, we propose a strategy of
femtosecond laser-assisted oxygen-rich doping to in situ create a
dense high-quality passivation layer on Al alloy surfaces. With respect
to the femtosecond laser processing in traditional air ambience, the
material surface modifications within the oxygen-rich environment
demonstrate some distinctiveness. For the ridge area of the laser
ablation grooves, the oxidation surface is separated into two layers:
the outer region presents a loose and porous appearance similar to
the observations in the air ambience, while the inner region exhibits
complete and homogeneous oxidation, especially associated with the
continuous distribution of the amorphous substance, in sharp contrast
to the nanoscale discrete amorphous formation in the air case. Simultaneously,
the high degree of material oxidization with the amorphous phase is
also developed on the wallside area of the groove valleys, which is
much different from the incomplete oxidation in the air ambience.
As a result, the measured corrosion current decreases by 49 times
to a value of I
corr = 1.19 × 10–10 A/cm2 relative to the laser treatment
in the air environment. Such a method offers the prospect for elevating
the anticorrosion performance of metal surfaces.