This article analyzes the influence of quenching in the wide temperature range on the amount of residual austenite, its stability and occurrence of deformation-induced martensite transformation, as well as the strengthening and wear resistance during abrasion of 150KhNML steel. Hardness and wear resistance of steels as a function of temperature are described by the curves with opposite trends, which is related with changes in content, composition of residual austenite and its deformation stability. The increase in relative wear resistance with quenching temperature is related to the microhardness of working surface after wear, which depends on the amount of formed nanocrystalline deformation-induced martensite. Formation of a secondary structure of steel working surface upon abrasion is determined by the cumulative action of friction and micro TWIP, as well as micro TRIP effects.