Infrared Spectroscopy of the ν1 Band of Sulfur Tetrafluoride, SF4

Raffael, Kevin D.; Smith, David M.

doi:10.1006/jmsp.2002.8570

Cited by 5 publications

(2 citation statements)

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“…The assignment and analysis of the n 1 , n 6 and n 8 fundamental bands of SF 4 have already been reported. 13 The n 2 band of SOF 2 was observed as a strong, partially resolved Q-branch centred at 808.2 cm À1 with weaker P-and R-branches to either side. Additional unresolved features were also observed at 807.2, 805.1 and 800.5 cm À1 .…”

Section: Resultsmentioning

confidence: 91%

“…See http://www.rsc.org/suppdata/cp/b2/b210153j/ spectroscopy and intramolecular dynamics of SF 4 . 13 The sample of SOF 2 used in this study was actually produced by the simple degradation through hydrolysis of a sample of SF 4 . An unpurified sample of SF 4 (Air Products, 94% purity by weight) was introduced into a 26 cm path length stainless-steel sample cell fitted with KBr windows through a glass and PTFE gas handling line.…”

Section: Methodsmentioning

confidence: 99%

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High-resolution Fourier-transform infrared spectroscopy of the ν2 fundamental band of thionyl fluoride, SOF2Electronic supplementary information (ESI) available: Tables S1 and S2. See http://www.rsc.org/suppdata/cp/b2/b210153j/

Davies

Newnham

Smith

2003

Phys. Chem. Chem. Phys.

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Section: Resultsmentioning

confidence: 91%

Section: Methodsmentioning

confidence: 99%

High-resolution Fourier-transform infrared spectroscopy of the ν2 fundamental band of thionyl fluoride, SOF2Electronic supplementary information (ESI) available: Tables S1 and S2. See http://www.rsc.org/suppdata/cp/b2/b210153j/

Davies

Newnham

Smith

2003

Phys. Chem. Chem. Phys.

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Fourier-transform infrared spectroscopy of the band of sulfur tetrafluoride,

Raffael

Smith

Newnham

2003

Journal of Molecular Spectroscopy

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Photochemical reaction of sulfur hexafluoride with water in low-temperature xenon matrices

Yamada

Tamura²,

Takeda³

2011

The Journal of Chemical Physics

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Sulfur hexafluoride SF(6) is a very stable molecule with which very few reactions with other molecules have been reported. Here, we report a photochemical reaction of SF(6) with water molecules using a matrix-isolation technique, where SF(6) and H(2)O were co-condensed in Xe matrices, and the products were observed using infrared spectroscopy. Irradiation at 193 nm from an ArF excimer laser caused the simultaneous decomposition of SF(6) and H(2)O, which resulted in the production of novel species. Infrared spectra and molecular orbital calculations of the species showed that the product was a SF(4)⋯HF⋯HOF complex, which consists of hydrogen bonds and charge transfer interaction between S and F atoms. The assignment of the species was confirmed by isotope shifts using D and (18)O isotope substitutions.

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Infrared Spectroscopy of the ν1 Band of Sulfur Tetrafluoride, SF4

Cited by 5 publications

References 23 publications

High-resolution Fourier-transform infrared spectroscopy of the ν2 fundamental band of thionyl fluoride, SOF2Electronic supplementary information (ESI) available: Tables S1 and S2. See http://www.rsc.org/suppdata/cp/b2/b210153j/

High-resolution Fourier-transform infrared spectroscopy of the ν2 fundamental band of thionyl fluoride, SOF2Electronic supplementary information (ESI) available: Tables S1 and S2. See http://www.rsc.org/suppdata/cp/b2/b210153j/

Fourier-transform infrared spectroscopy of the band of sulfur tetrafluoride,

Photochemical reaction of sulfur hexafluoride with water in low-temperature xenon matrices

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