The corrosion inhibition efficiency (IE) of an aqueous extract Allium cepa (onion) in controlling the corrosion of carbon steel ground water in absence and presence of with Zn 2+ has been studied by weight loss method. The formulation consisting of 3 mL Allium cepa extract, 50 ppm of Zn 2+ and 50 ppm of sodium pattassium tartarate which offers 97% inhibition efficiency. The synergistic effect exists between onion-Zn 2+-tartarate system. The addition of N-cetyl-N,N,Ntrimethylammonium bromide on onion-Zn 2+-tartarate system does not change the excellent inhibition efficiency. Polarization study shows that the onion-Zn 2+-tartarate system functions as a cathodic inhibitor. AC impedance spectra reveal that a protective film is formed on the metal surface. The UV fluorescent spectra indicate the possibility of formation of Fe 2+-onion complex and also Zn 2+-onion complex in solution. Thus the protective film is found to be UV fluorescent.