Exploring suitable types and intensities of environmental regulations to promote technological innovation and guide industrial green growth is an essential goal for China. This paper uses the SBM super-efficiency model with the GML index to measure the level of green growth in China’s citrus industry from 2008 to 2019, and examines the impact generated by heterogeneous environmental regulations and the mediating effect of technological innovation using a panel Tobit model. The study found that: (1) From 2008 to 2019, the green growth level of the citrus industry has gradually improved, with an average annual growth rate of 2.7%, and the contribution of technical efficiency is more significant than technological progress. (2) The green growth of the citrus industry is closely related to the intensity and type of environmental regulation. The impact of market-incentive environmental regulation has an inverted U-shape, the impact of guidance-based environmental regulation is U-shaped, and the command-and-control environmental regulation has no significant effect. (3) The mediating effect suggests that guidance-based environmental regulation promotes green growth in the citrus industry by stimulating technological innovation. In contrast, market-incentive environmental regulation inhibits technological innovation and thus discourages green growth in the citrus industry. According to the study results, the government should strive to ensure the effective implementation of environmental laws and regulations, optimize the channels and amounts of investment in environmental governance, strengthen environmental protection-related media campaigns, and guide the citrus industry to break through technological bottlenecks to promote green growth.