We devise and experimentally realize a procedure capable to detect and distinguish quantum discord and classical correlations, as well the presence of factorized states in a joint system-environment setting. Our scheme builds on recent theoretical results showing how the distinguishability between two reduced states of a quantum system in a bipartite setting can convey important information about the correlations present in the bipartite state and the interaction between the subsystems. The two addressed subsystems are the polarization and spatial degrees of freedom of the signal beam generated by parametric downconversion, which are suitably prepared by the idler beam. Different global and local operations allow for the detection of different correlations by studying via state tomography the trace distance behavior between suitable polarization subsystem states.The study of a bipartite system is an ever present theme which has led to important advancements in the understanding of quantum mechanics, especially when the two parties cannot be put on an equal footing. The prototypical situation is a measurement interaction, in which the interest is all on the side of the system, calling for tools and ideas allowing for an ever improving description of such interactions [1]. The theory of open quantum systems has provided a natural extension of these efforts, in which the quantum features of the measurement apparatus are put in major evidence [2], while correlations between system and environment have received important attention only more recently, thanks to the consolidation of quantum information theory [3]. The latest theoretical developments as well as the refinement in the experimental techniques has led to a change of paradigm in facing the system-environment (SE) dynamics. The possibility has been envisaged of actually exploiting the open quantum system, supposed to be liable to a relatively easy and accurate experimental observation, as a quantum probe of features of the environment, typically to be considered as a complex system. Properties of the environment which might be unveiled by an observation on the system up to now include the detection of quantum phase transitions [4], as well as the assessment of correlations within the state of the environment [5]. These advancements have been based on the study in time of the distinguishability of different initial system states [6], which has proven to be a fruitful strategy in order to exploit a quantum system as probe of features of a bipartite dynamics [7][8][9][10][11][12][13].In this paper we improve this approach to devise a novel method for the determination of quantum correlations, which play a crucial role both in quantum information and in the development of quantum technologies. The approach is based on a two-step procedure, which relying on measurements on the system only allows to determine whether a given initial SE state actually contains quantum correlations, as quantified by quantum discord or, if this is not the case, decide whether it contai...