Luminescent materials (or phosphors) are generally characterized by the emission of light with energy beyond thermal equilibrium. More vividly this means: The nature of luminescence is different from that of black-body radiation. Luminescence can occur as a result of many different kinds of excitation, which is reflected in expressions such as photo-, electro-, chemi-, thermo-, sono-, or triboluminescence. In practice, most often the excitation is via X-rays, cathode rays, or UV emission of a gas discharge. The role of the phosphor is to convert the incoming radiation into visible light. In addition to the type of excitation, two other terms are used quite often to classify luminescent materials. Both can be related to the decay time (s): fluorescence (s < 10 ms) and phosphorescence (s > 0.1 s). [1] The luminescence of inorganic solids, which is the focus of this contribution, can be traced to two mechanisms: luminescence of localized centers and luminescence of semiconductors (Fig. 1). [1,2] The first case is represented by transitions between energy levels of single ions (e.g., f±f transitions of Eu 3+ in Y 2 O 3 :Eu 3+ ) or complex ions (e.g., the charge-transfer transition on [WO 4 ] 2± in CaWO 4 ). In the case of luminescent centers, the transition rate is (more or less strongly) correlated to the relevant quantum-mechanical selection rules, and reflected in the intensity as well as the decay time of the transition. Excitation and emission can be (as shown in Fig. 1) both localized to one center (e.g., [WO 4 ] 2± in CaWO 4 ) or separated from each other: excitation on sensitizer (e.g., Ce 3+ in LaPO 4 :Ce 3+ ,Tb 3+ ) is followed by emission on activator (e.g., Tb 3+ in LaPO 4 :Ce 3+