This research activity aims to evaluate electrical insulation system (EIS) intended for electrical machine winding wires. The evaluation is based on mechanical, thermal, and electrical properties tests following international standards for enameled wires. Dielectric parameters such as dissipation factor, partial discharge inception voltage (PDIV), parallel capacitance, and parallel resistance behavior of different insulator configurations on twisted-pair samples are observed during thermal aging tests. Those configurations are formed of different combinations of dielectric layers based on conventional polymers (polyester-imide (PEI), polyamide-imide (PAI), polyimide (PI)) used as coating wires. A study using two mineral varnishes (silica-based) obtained by the sol-gel process integrated on these classical enamels an outer layer of extrusion of thermoplastic polymer with and without mineral fillers. Given the high consummation of energy and the use of unsustainable materials involving the production of wires, the principal interest of this work is to exploit new configurations of coating wire produced, with less environmental impact than conventional ones. This work investigates the impact of filled resins on the performance of insulating samples and the influence of the use of sol-gel solutions (mineral varnishes) on the insulated wire to increase the thermal class.