Water-based superamphiphobic coatings that are environmentally
friendly have attracted tremendous attention recently, but their performances
are severely limited by dispersibility and mechanical durability.
Herein, a dispersion of poly(tetrafluoroethylene)/SiO2@cetyltrimethoxysilane&sodium
silicate-modified aluminum tripolyphosphate (PTFE/SiO2@CTMS&Na2SiO3-ATP) superamphiphobic coatings was formed
by mechanical dispersion of poly(tetrafluoroethylene) emulsion (PTFE),
modified silica emulsion (SiO2@CTMS), sodium silicate (Na2SiO3), and modified aluminum tripolyphosphate (modified
ATP). The four kinds of emulsions were mixed together to effectively
solve the dispersity of waterborne superamphiphobic coatings. Robust
waterborne superamphiphobic coatings were successfully obtained by
one-step spraying and curing at 310 °C for 15 min, showing strong
adhesive ability (grade 1 according to the GB/T9286), high hardness
(6H), superior antifouling performance, excellent impact resistance,
high-temperature resistance (<415 °C), anticorrosion (immersion
of strong acid and alkali for 120 h), and heat insulation. Remarkably,
the prepared coating surface showed superior wear resistance, which
can undergo more than 140 abrasion cycles. Moreover, the composite
coating with 35.53 wt % SiO2@CTMS possesses superamphiphobic
properties, with contact angles of 160 and 156° toward water
and glycerol, respectively. The preparation method of superamphiphobic
coatings may be expected to present a strategy for the preparation
of multifunctional waterborne superamphiphobic coatings with excellent
properties and a simple method.