“…Depending on the chemical/electrical nature of the substrate and the oil-water interface the surface charge may also change during approach by ion exchange [2][3][4][5][6][7] as the counterions are driven towards and adsorbed by the negatively charged droplet and/or the substrate [2][3][4][5][6][7][8][9][10][11]. A summation of the entropic and the short ranged van der Waal force is designated the DLVO interaction [1][2][3][4][5][6][7][8][9][10][11]. Other possible forces of interaction are capillary forces [11], hydration forces [10,11,13,14] and hydrophobic attraction which may be short ranged (0-10 nm) or long ranged ($30 nm) [5,11,12].…”