Interaction of tri-tert-butylgallium with elemental sulfur, selenium, and tellurium

Synthesis and characterization of gallium thiocarboxylates as novel single-source precursors to gallium sulfide thin films by aerosol-assisted CVD

“…The analytical and spectroscopic data for 1 were all consistent with the solid-state X-ray diffraction results and other structurally characterized Ga compounds. [18][19][20] In contrast, the reaction of GaEt3 with 3.0 equiv. of thioacetic acid in toluene in the presence of dmpy gave rise to the formation of Ga(SCOMe)3(dmpy).…”

Synthesis and Application of Monomeric Chalcogenolates of 13 Group Elements

“…In the 77 Se NMR spectra of 8 and 9 , the signals at δ =459.5 ( 8 ) and 2.5 ( 9) ppm were found and fall into the broad range observed for organometallic selenolates . However, the signals of 8 (459.5 ppm) and of 9 (2.5 ppm) are shifted downfield in comparison to related complexes [ t Bu 2 Ga(μ‐Se t Bu)] 2 (156 ppm) and Mes 2 ln(μ‐SeR) (R=Me, Ph, Mes) (range from −56 to −160 ppm) having the SeR bridging groups. This may be the consequence of monomeric nature 8 and 9 .…”

1. Introduction of selenium and tellurium into reaction systems

“…The formation of a B=Te double bond[121].An excess of elemental tellurium in refluxing toluene reacts with M( t Bu)3 (M = Al, Ga) to form the cubane [M( t Bu)(µ3-Te)]4 and t BuTeTe t Bu[122,123] (seeFigure 14). The structure of the tetramericcage molecule was deduced by comparison of the spectroscopic properties with those of [M( t Bu)(µ3-Se)]4 and [M( t Bu)(µ3-S)]4.…”