With
the rapid development of modern intelligent industry and the
Internet of Things, the demand for multifunctional electromagnetic
interference (EMI) shielding material has increased for complicated
application scenes. Herein, derived from a hazardous waste, i.e.,
leather solid waste (LSW), a silver/LSW/poly(vinyl alcohol) (PVA)
membrane has been prepared via resourceful combination of solids state
shear milling (S3 M) and electroless plating technology.
The debundled leather fibers prepared by S3 M can act as
template for silver electroless plating and thus conductive Ag/LSW
fibers with high aspect ratio and electrically conductive were achieved.
Moreover, Ag/LSW fibers were integrated into film and sealed with
PVA to form the Ag/LSW/PVA membrane. Owing to the high conductivity
and mechanical performance of PVA, the Ag/LSW/PVA membrane (1.2 mm)
exhibited EMI shielding (62 dB), mechanical robustness (tensile strength
reached to 89.7 MPa), and Joule heating capability (56 s to 101.3
°C). Impressively, the multifunctional membrane exhibits great
potential in future smart oil stations, where under the premise of
satisfying high-efficiency electromagnetic shielding, the Ag/LSW/PVA
membrane can effectively absorb heavy crude oil through the Joule
heating and porous structure and achieve double protection for electronic
devices.