Intercalation of alkylammonium ions and oxide layers |TiNbOt|−

Elaboration of Poly(ε‐caprolactone)‐g‐TiNbO5 Nanocomposites via in situ Metal Complex Initiated Intercalative Polymerization

“…These values are the same as those documented in the literature and the a and b parameters are practically independent of the intercalated cation type. [10] The interlayer distance d 002 corresponding to half of the c parameter in an orthorhombic system can be considered as equal to 8.345 Å . The proton exchange process between HTiNbO 5 and AlMe 3 cannot be identified by WAXS because the modest steric hindrance of the latter complex allows it to penetrate into the gallery without inducing an increase of the interlayer distance.…”

“…more or less voluminous, up to one organic molecule per proton, without destroying the bidimensional layers. [10] Several studies have demonstrated the great flexibility of the HTiNbO 5 structure. The a and b parameters (6.53 Å and 3.78 Å , respectively) determined by the geometry of TiNbO 5 layers remain independent of the cation nature.…”

Rheological characterization of polydimethylsiloxane/HTiNbO5 nanocomposites prepared by different routes

“…In this work, we used synthetic mineral oxide HTiNbO 5 , that was preferred to layered silicates because of its perfect lamellar structure and for its well-defined chemical structure, contrary to layered silicate clays [8]. Furthermore, several studies have demonstrated the possibility of intercalation of voluminous organic molecules inside HTiNbO 5 galleries [9,10].…”

Elaboration and characterization of novel polyamide-12-layered titanoniobates nanocomposites

“…In the present work, we examine the formation of polyamide nanocomposites by the incorporation of KTiNbO 5 , 26 which is a filler that has rarely been used in polymers. [27][28][29] This inorganic material, which has been extensively studied in our laboratory, [30][31][32][33][34] is characterized by its high cationic exchange capacity leading, after organomodification, to a high density of alkylammonium surfactant molecules. The questions addressed in the present work concern the structure and properties of the nanocomposites formed by KTiNbO 5 dispersion in PA12.…”