The structural, electronic,
and magnetic properties of Sr-hole-doped
epitaxial La
1–
x
Sr
x
MnO
3
(0.15 ≤
x
≤
0.45) thin films deposited using the molecular beam epitaxy technique
on 4° vicinal STO (001) substrates are probed by the combination
of X-ray diffraction and various synchrotron-based spectroscopy techniques.
The structural characterizations evidence a significant shift in the
LSMO (002) peak to the higher diffraction angles owing to the increase
in Sr doping concentrations in thin films. The nature of the LSMO
Mn mixed-valence state was estimated from X-ray photoemission spectroscopy
together with the relative changes in the Mn L
2,3
edges
observed in X-ray absorption spectroscopy (XAS), both strongly affected
by doping. CTM4XAS simulations at the XAS Mn L
2,3
edges
reveal the combination of epitaxial strain, and different MnO
6
crystal field splitting give rise to a peak at ∼641
eV. The observed changes in the occupancy of the e
g
and
the t
2g
orbitals as well as their binding energy positions
toward the Fermi level with hole doping are discussed. The room-temperature
magnetic properties were probed at the end by circular dichroism.