Internal Oxidation of a Fe–Cr Binary Alloy at 700–900 °C: The Role of Hydrogen and Water Vapor

Abstract

Internal oxidation of Fe–2.25Cr has been studied in Fe/FeO Rhines pack (RP) and H2/H2O gas mixtures at 700–900 °C. A novel exposure technique allowing RP experiments in dual atmosphere conditions was developed. No measurable effect of hydrogen on lattice oxygen permeability in ferrite could be detected: neither in single nor in dual atmosphere conditions. The H2/H2O atmosphere was found to induce stronger oxidation attack at alloy grain boundaries resulting in a morphology similar to intergranular stress corrosion cracking often reported in nuclear technology. The intergranular oxidation attack was demonstrated to be independent of the dual atmosphere effect, i.e., hydrogen dissolved in the alloy.

Oxidation Behavior of Pure Iron under Hydrogen Combustion Environment

“…Although there have been many reports on the oxidation behavior of metals in mixed atmospheres of hydrogen, oxygen, and water vapor [9][10][11][12][13][14][15][16][17][18][19][20][21][22][23][24][25][26][27], there are no reports on the measurement of hydrogen behavior in situ. Water vapor and oxygen are both involved in oxidation and generate similar oxides.…”