2020
DOI: 10.1002/aenm.202002214
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Interplanar Growth of 2D Non‐Van der Waals Co2N‐Based Heterostructures for Efficient Overall Water Splitting

Abstract: The highly efficient water splitting is characterized by low overpotential, low Tafel slope, and long cyclability for both OER and HER, where OER is the bottleneck. In order to lower the energy barrier of four-electron transfer OER process (4OH-↔ 2H 2 O + O 2 + 4e-), the major challenge is to fabricate the catalyst that could form the optimized oxygen binding with intermediate adsorbates, which should be neither too strong nor too week to balance the energetics of the processes between the deprotonation of OH*… Show more

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Cited by 48 publications
(19 citation statements)
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“…However, the scarcity, high price and poor stability have limited their largescale applications. 7,8 Besides, most effective catalysts are mono-functional, either for HER or for OER catalysis, because the activity and stability of the catalysts are inadequate for both processes in the same media. Therefore, it is imperative to develop bifunctional electrocatalysts with low cost, high catalytic activity, and good stability to achieve efficient and simultaneous hydrogen production.…”
Section: Introductionmentioning
confidence: 99%
“…However, the scarcity, high price and poor stability have limited their largescale applications. 7,8 Besides, most effective catalysts are mono-functional, either for HER or for OER catalysis, because the activity and stability of the catalysts are inadequate for both processes in the same media. Therefore, it is imperative to develop bifunctional electrocatalysts with low cost, high catalytic activity, and good stability to achieve efficient and simultaneous hydrogen production.…”
Section: Introductionmentioning
confidence: 99%
“…However, efficient water splitting is characterized by low overpotential, low Tafel slope, and excellent cycling stability for a long lime. The OER is more challenging of the two reaction processes due to four-electron transfer reactions, whereas the HER is a two-electron proton-coupled reaction. , Thus, developing a highly efficient electrocatalyst is highly challenging, which could form the electroactive oxygenated species on the catalyst surface in the intermediate step. , Notably, heteroatom-based catalysts are more efficient for forming oxygen binding energy, enhancing the performance of overall water splitting. …”
Section: Introductionmentioning
confidence: 99%
“…The fascinating anisotropic and unique electronic properties of two-dimensional (2D) materials have sparked tremendous research interest in their potential applications in energy storage, catalysis, electronics, etc.1 Particularly, owing to the abundant active sites resulting from the large specic surface area and the increased electron density of states around the Fermi energy induced by the anisotropic in-plane properties, 1 2D nanomaterials have been extensively investigated in electrocatalysis, which represents one of the key technologies in clean energy conversion and storage systems. 2,3 Developing appropriate synthetic methods is a prerequisite for the study of 2D nanomaterials. The traditional principle for deriving 2D structures from bulk materials involves the exfoliation of layered materials by weakening the interactions between the layers, either via mechanical force-assisted exfoliation or through intercalation-induced lattice expansion.…”
Section: Introductionmentioning
confidence: 99%