The sequential two-proton decay of the second excited state in 17 Ne, produced by inelastic excitation at intermediate energy, is studied. This state is found to be highly spin aligned, providing another example of a recently discovered alignment mechanism. The fortuitous condition that the second decay step is slightly more energetic than the first, permits the lifetime of the one-proton daughter, the ground-state of 16 F, to be determined from the magnitude of the final-state interactions between the protons. This new method gave a consistent result [Γ=20.6(57) keV] to that obtained by directly measuring the width of the state [Γ=21.3(51) keV]. This width allows one to determine the continuum coupling constant in this mass region. Real-energy continuum-shell-model studies yield a satisfactory description of both spectra and widths of low-energy resonances in 16 F and suggest an unusual large ratio of proton-proton to proton-neutron continuum couplings in the vicinity of the proton drip line.