Investigating the plasmonics of a dipole-excited silver nanoshell: Mie theory versus finite element method

Abstract

This report compares COMSOL's finite element method (FEM) algorithm with the Mie theory for solving the electromagnetic fields in the vicinity of a silica-silver core-shell nanoparticle when excited by a radiating dipole. The novelty of this investigation lies in the excitation source of the nanoshell system: an oscillating electric dipole is frequently used as a model for both molecular scattering and molecular fluorescence; moreover, a common classical model of atomic or molecular spontaneous emission is a decaying electric dipole. The radiated power spectra were evaluated both analytically and numerically by integrating the Poynting vector around 20, 60 and 100 nm nanoshells, thereby solving the total and scattered fields generated by a dipole positioned inside the core and in the surrounding air medium, respectively. The agreement was excellent in amplitude, plasmon resonance peak position and full width at half-maximum. The FEM algorithm also generates accurate solutions of the near-field electromagnetics in the spatial domain, where the E-field behavior as a function of polar angle theta for a fixed observation radius was evaluated. The quasistatic approximation, which is valid for small nanoparticles, is also employed to assess its limitations relative to the Mie and FEM algorithms.

Gold nanostars: surfactant-free synthesis, 3D modelling, and two-photon photoluminescence imaging

“…Instead of modelling the plasmon of a single polarization, our analysis features polarization-averaging over space as the nanostars were discretely rotated at six angles, a feature that has not been addressed so far. The 3D nanostar simulations were performed using the FEM, which yields solutions to the local E-field around 3D metallic nanostructures that are in excellent agreement with the theory [66, 67]. …”

Fluorescence quenching of osthole by silver nanoparticles

“…The dielectric constant of silver nanoparticles was adopted with the amended form in the simulation process [29]. The expression of the amended dielectric constant is shown as follows:…”

Fabrication and optical thermometry of transparent glass‐ceramics containing Ag@NaGdF4: Er3+ core‐shell nanocrystals

“…Luminescence spectra were obtained by the Acton SpectraPro Sp-2300 Spectrophotometer with a photomultiplier tube equipped with 980 nm laser as the excitation sources. [25][26][27] The upconversion emission spectra of 0.15%Ag@NaGdF 4 :Er 3+ excited by 980 nm infrared laser are shown in Figure 2B. As shown in Figure 1A, the circular nanoparticles were uniformly distributed in the glass-ceramic matrix.…”