Investigating the use of porous, hollow glass microspheres in positive lead acid battery plates

Sorge, Matthew; Bean, Thomas; Woodland, Travis; Canning, John R.; Cheng, I-Chun; Edwards, Dean B.

doi:10.1016/j.jpowsour.2014.05.021

Cited by 15 publications

(13 citation statements)

References 23 publications

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“…Dalai et al [94] pointed out that a suitable metal loading in required proportion on the HGMs assists in improving the hydrogen storage capacity. As reported in the publication of Sorge et al [95], the PHGM additives did enhance electrolyte storage and porosity in the electrodes. Dalai et.al.…”

Section: The Latest Studies On Glass Microspheressupporting

confidence: 56%

Glass Microspheres

Karasu

DEMİREL

ÖZTUVAN

et al. 2019

El-Cezeri Fen Ve Mühendislik Dergisi

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Glass microspheres are microscopic spheres of glass manufactured for a wide variety of uses in thermal insulation coating, putty, plastic casting polyester, radome, synthetic foam, adhesives, printed circuit board substrate, bowling, fan blades, and caulking materials, emulsion explosives, golf, sealant, pipeline insulation materials, artificial marble, PVC, low density oil drilling, light cement etc. Glass microspheres are usually between 1 and 1000 micrometres in diameter, although the sizes can range from 100 nanometres to 5 millimetres in diameter. Microspheres are spherical particles that can be distinguished into two categories; solid or hollow. This paper presented a general overview of glass microspheres.

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Section: The Latest Studies On Glass Microspheressupporting

confidence: 56%

Glass Microspheres

Karasu

DEMİREL

ÖZTUVAN

et al. 2019

El-Cezeri Fen Ve Mühendislik Dergisi

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“…[5][6][7] After all these procedures the lead oxides containing 70-80% PbO and 20-30% Pb are finally transformed into PbO 2 and Pb. [5][6][7] After all these procedures the lead oxides containing 70-80% PbO and 20-30% Pb are finally transformed into PbO 2 and Pb.…”

mentioning

confidence: 99%

Comment on “Environmentally responsible fabrication of efficient perovskite solar cells from recycled car batteries” by Po-Yen Chen, Jifa Qi, Matthew T. Klug, Xiangnan Dang, Paula T. Hammond and Angela M. Belcher, Energy Environ. Sci., 2014

Yuan

et al. 2015

Energy Environ. Sci.

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A paper published in Energy and Environmental Science by Po-Yen Chen et al. reported on a new route for fabricating perovskite solar cells using ''recycled car batteries'' (spent lead acid batteries) as starting materials. Multiple lines of evidence show that it was a new lead acid battery and not a recycled one that was used to synthesize lead iodide perovskite materials in this work. As the components of electrodes are different between new batteries and spent ones, this fabricating method would not be applicable for use in recycled car batteries.

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“…According to Table , the Faraday efficiency of the LOC–DSC solar battery is 3.8%, which is too low for any electrical storage device including lithium ion or lead–acid batteries . Based on our analysis, the low faraday efficiency is mainly caused by the competitive reaction of I − /I 3 − with lead redox reactions in LOC electrolyte when the LOC–DSC is under illumination (see the Supporting Information for more details).…”

Section: Resultsmentioning

confidence: 89%

Solar Rechargeable Batteries Based on Lead–Organohalide Electrolyte

Wang

Chen

McFarland

et al. 2015

Advanced Energy Materials

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and electron transporter. [ 6 ] In addition, photocorrosion of the semiconductor photoelectrodes limits the lifetime. [ 7 ] Inspired by the largely improved performance of dye-sensitized solar cells (DSCs) using a mesoporous TiO 2 -photoanode, [ 8 ] a hybrid DSC was developed with an electrochemical cell or supercapacitor for storage. [ 9 ] In one design, a lithium intercalation electrode of WO 3 is hybridized with a typical DSC in a three-electrode-type confi guration. [ 10 ] WO 3 is selected as the chargestorage material because of its well-known special optical and electrical response that are caused by the reversible insertion/ extraction of H + and alkali metal ions. [ 11 ] Hiroki et al. built a solar rechargeable solar cell based on a polypyrrole electrode as the accessory electrode to DSCs. [ 12 ] The polypyrrole fi lm makes use of a reversible doping reaction, which is found to be suitable for charge storage in an electrochemical cell. This type of solar battery has a complex design and low performance. [ 12,13 ] Another solar battery design is a rechargeable fl ow battery (RFB) that utilizes a pair of soluble redox couples that can be regenerated by fl owing through a DSC. [ 14 ] The required electrolyte pumps for the two electrolytes consumed signifi cant fractions of the cell energy and the overall energy harvesting and utilization effi ciency is relatively low. In the submission of this manuscript, Yu et al. [ 15 ] designed a lithium-oxygen battery integrated with a redoxcoupled dye-sensitized photoelectrode, which can realize the photoassisted charging of the system. However, external power supply is still needed for charging the lithium-oxygen battery.Herein, we demonstrate a simple DSC-based device, which in situ stores electricity using a lead-organohalide electrolyte, CH 3 NH 3 I·PbCl 2 (LOC), in N , N -dimethylformamide (DMF) as the electrolyte. It has been recently reported that the lead-organohalide-based perovksite fi lms deposited from these solutions can be used as an excellent light absorber in solid-state solar cells (SSCs), [ 16 ] which have triggered exponentially increased research effort on this family of perovskite materials and certifi ed effi ciency of over 20% for SSCs has been reported. [ 17 ] Unlike most of the reported studies that used the deposited perovskite fi lms as light absorbers in SSCs, we explored the properties of lead-organohalide solution by applying it as a new type of electrolyte in a DSC. CH 3 NH 3 I·PbCl 2 (LOC) electrolyte was found to function as an excellent electrolyte as competitive as a conventional triiodide electrolyte, presenting a considerably good stability over the time. [ 18 ] Continued on this work, here we present our new A dye-sensitized solar cell (DSC) with in situ energy storage capacity is demonstrated using a lead-organohalide electrolyte CH 3 NH 3 I·PbCl 2 (LOC) to replace the conventional I − /I 3 − electrolyte. The coupling of lead and iodine in one electrolyte creates a dual-function rechargeable solar battery that combines the workin...

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Investigating the use of porous, hollow glass microspheres in positive lead acid battery plates

Cited by 15 publications

References 23 publications

Glass Microspheres

Glass Microspheres

Comment on “Environmentally responsible fabrication of efficient perovskite solar cells from recycled car batteries” by Po-Yen Chen, Jifa Qi, Matthew T. Klug, Xiangnan Dang, Paula T. Hammond and Angela M. Belcher, Energy Environ. Sci., 2014

Solar Rechargeable Batteries Based on Lead–Organohalide Electrolyte

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